People

Alexander S. Antonov

foc Antonov ASPhD, Senior researcher in Southern Federal University (Internship in St. Petersburg State University)

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tel.: 007-904-5009756
office 1072

ORCID: 0000-0001-7047-789X
Scopus ID: 56201232900

Research interests

  • Organometallic chemistry (lithium, copper, boron)
  • Chemistry of heterocyclic compounds
  • Organic superbases
  • Non-covalent interactions (hydrogen bond, agostic interaction)

Сurriculum vitae

  • 2017–2018 — Member of the Academic Senate in the Faculty of Chemistry at the Southern Federal University (Rostov-on-Don).
  • 2017–present — Chairman of the Young Researchers Council in the Faculty of Chemistry at the Southern Federal University (Rostov-on-Don).
  • 2016–present — Senior researcher at the Department of Organic Chemistry in the Faculty of Chemistry at the Southern Federal University (Rostov-on-Don).
  • 2015–2016 — Deputy Dean for research in the Faculty of Chemistry at the Southern Federal University (Rostov-on-Don).
  • 2012–2015 — Deputy Chairman of the Young Researchers Council in the Faculty of Chemistry at the Southern Federal University (Rostov-on-Don).
  • 2012–2015 — Assistant at the Department of Organic Chemistry in the Faculty of Chemistry at the Southern Federal University.  (Rostov-on-Don).
  • 2011–2014 — PhD student at the Department of Organic Chemistry in the Faculty of Chemistry at the Southern Federal University. Supervisor: Dr. Prof. A.F. Pozharskii (Rostov-on-Don).
  • 2009–2011 — Master student at the Faculty of Chemistry at the Southern Federal University. (Rostov-on-Don).
  • 2008–2015 — Laboratory assistant at the Scholl Nr 5 (Rostov-on-Don).
  • 2005–2009 — Bachelor student at the Faculty of Chemistry at the Southern Federal University. (Rostov-on-Don).

Grants

  • Grant of the Russian Foundation for Basic Research № 16-33-60030 «Organometallic derivatives of 1,8-bis(dimethylamino)napthalene» (2016-2018).
  • Grant of the Russian Foundation for Basic Research № 12-03-31172 «New principle of pyrrole ring construction: synthesis of benzo[g]indoles » (2011-2012).
  • Travel-grant of the Russian Foundation for Basic Research № 12-03-09399 for the participation in XXVth European Colloquium on Heterocyclic Chemistry with report “Two kinds of heterocyclisation in proton sponges leading to the formation of naphtho[2,1-d]isoxazoles and benzo[g]indol derivatives”, Reading (UK), August 13-17 2012.

Publications

  • Antonov, A.S., Bardakov, V.G., Pozharskii, A.F., Vovk, M.A., Misharev, A.D. «Laying the way to meta-functionalization of naphthalene proton sponge via the use of Schlosser's superbase» Journal of Organometallic Chemistry, 2018, 855, 18–25.
  • Antonov, A. S., Kachalkina, S. G., Pozharskii, A. F., Borodkin, G. S., Filarowski, A. «Reaction of 2-Trifluoroacetyl-1,8-Bis(dimethylamino)naphthalene with Strong Organic Bases: Acidic Ionization of 1-NMe2 Group Resulting in the Formation of Benzo[g]indole Derivatives versus Nucleophilic Addition to C=O Group» Tetrahedron, 2017, 73, 3452–3457.
  • Mikshiev, V. Y., Antonov, A. S., Pozharskii, A. F. «Tandem synthesis of 10- dimethylaminobenzo[h]quinazolines from 2-ketimino-1,8-bis(dimethylamino)naphthalenes via nucleophilic replacement of the unactivated aromatic NMe2 group» Organic Letters, 2016, 18, 2872–2875.
  • Pozharskii, A. F., Ozeryanskii, V. A., Mikshiev, V. Y., Antonov, A. S., Chernyshev, A. V., Metelitsa, A. V., Borodkin, G. S., Fedik, N. S., Dyablo, O. V. «10-Dimethylamino derivatives of benzo[h]quinoline and benzo[h]quinazolines: fluorescent proton sponge analogues with opposed peri-NMe2/–N= groups. How to distinguish between proton sponges and pseudo-proton sponges» Journal of Organic Chemistry, 2016, 81, 5574–5587.
  • Kachalkina, S. G., Borodkin, G.S., Pozharskii, A. F., Antonov, A. S., Borodkina, I. G., Maltsev, Y. F., Filatova, E. A., Filarowski, A., Ozeryanskii, V. A. «Base-promoted transformation of 2-C(O)R-1,8-bis(dimethylamino)naphthalenes into benzo[g]indole derivatives» Mendeleev Communications, 2015, 25, 182–184.
  • Antonov, A. S., Pozharskii, A. F., Ozeryanskii, V. A., Filarowski, A., Suponitsky, K. Yu., Tolstoy, P. M., Vovk, M. A. «Ring lithiation of 1,8-bis(dimethylamino)naphthalene: another side of the „proton sponge coin”» Dalton Transactions, 2015, 44, 17756–17766.
  • Ozeryanskii, V. A., Pozharskii, A. F., Antonov, A. S., Filarowski, A. «Out-Basicity of 1,8-bis(dimethylamino)naphthalene: The experimental and theoretical challenge»  Organic and Biomolecular Chemistry, 2014, 12, 2360–2369.
  • Antonov, A. S., Mikshiev, V. Y., Pozharskii, A. F., Ozeryanskii, V. A. «Ortho-ketimines of 1,8-bis(dimethylamino)naphthalene: Synthesis, hydrolytic stability and transfer of basicity from proton sponge moiety to the imino function» Synthesis, 2014, 46, 3273–3282.
  • Povalyakhina, M. A., Antonov, A. S., Dyablo, O. V., Ozeryanskii, V. A., Pozharskii, A. F.  «H-bond-assisted intramolecular nucleophilic displacement of the 1-NMe2 group in 1,8-bis(dimethylamino)naphthalenes as a route to multinuclear heterocyclic compounds and strained naphthalene derivatives» Journal of Organic Chemistry, 2011, 76, 7157–7166.