Synthesis and Investigation of Nanoparticles and Nanostructured Materials Group

Research Interests

The main scientific idea

Regulation of morphology and chemical composition of inorganic nanoparticles of various nature as a mechanism for controlling their functional properties and functional properties of materials based on them.

Chemistry & Materials Science

Development of chemical approaches to the regulation of the morphology and properties of inorganic nanoparticles during their synthesis from solutions and a comprehensive study of the relationship between the morphological features of nanoscale objects and their physical and physicochemical properties

Computational experiment

Application of computational methods for characterization of the obtained objects and processes occurring in the reaction medium

Chemical design of nano-objects and nanomaterials based on them

Controlable change in the morphological parameters of individual nanoparticles and composites based on them to obtain the specified functional properties (including the hybrid nanomaterials production).

The results of ongoing fundamental research are further used to develop

• agents for MRI, hyperthermia and magnetic separation based on biocompatible iron oxides;
• biocompatible ceramics (including dual functionality) and polymer-inorganic composites for bone tissue engineering;
• "smart" glass coatings;
• materials for ultra-high density magnetic recording media;
• sorbents and catalysts;
• materials for lithium-ion batteries and electrochemical power sources;
• materials for thermosensitive elements;
• components of paint and varnish coatings and sorbents with antibacterial activity.

Research Directions and Projects

Research directions

• Inorganic nanoparticles with different morphological parameters as stabilizers of colloidal systems
• The relationship "composition – structural characteristics – optical properties" in nanoparticles of doped wide-gap oxide semiconductors of various morphologies
• Optimization of the target physical and chemical properties of the material due to the rational design of composites of complex structure based on inorganic nanoparticles of various chemical nature
• Regulation of the functional properties of core-shell nanoparticles by controlled variation of the components morphological parameters
• Nanoparticles of biocompatible calcium phosphates of various morphologies and their application for medicine, biotechnology and the cosmetic industry

Supported projects

RFBR grant 18-03-01066 Development of a promising general approach to the magnetite nanoparticles modification to obtain new multifunctional materials for in vitro and in vivo diagnostics and personalized medicine

RFBR grant 20-03-00762 Development of an approach to computer simulation of nanoparticles growth processes in solutions: theoretical and experimental case study of tin oxide – photocatalytic material

Publications

2020 год

1. Theoretical and experimental approaches to the electro-optical study of boehmite nanoparticles with given morphology Osmolovskaya, O.M., Osmolowsky, M.G., Petrov, M.P., Voitylov, A.V., Vojtylov, V.V. Colloids and Surfaces A: Physicochemical and Engineering Aspects 586,124095 https://www.sciencedirect.com/science/article/abs/pii/S0254058419305449?via%3Dihub IF 3.99, Q1
2. Capping agents as a novel approach to control VO₂ nanoparticles morphology in hydrothermal process: Mechanism of morphology control and influence on functional properties Petukhova, Y.V., Kudinova, A.A., Bobrysheva, N.P., Osmolowsky, M.G., Alekseeva, E.V., Levin, O.V., Osmolovskaya, O.M. Materials Science and Engineering B: Solid-State Materials for Advanced Technology 255,114519 https://www.sciencedirect.com/science/article/abs/pii/S092151072030026X?via%3Dihub IF 4.706, Q1
3. Morphology and doping concentration effect on the luminescence properties of SnO₂:Eu³⁺ nanoparticles Kolesnikov, I.E., Kolokolov, D.S., Kurochkin, M.A., Voznesenskiy, M.A., Osmolowsky, M.G., Lähderanta, E., Osmolovskaya, O.M. Journal of Alloys and Compounds 822,153640 https://www.sciencedirect.com/science/article/abs/pii/S0925838820300037 IF 4.65, Q1
4. Magnetic headspace adsorptive microextraction using Fe₃O₄@Cr(OH)₃nanoparticles for effective determination of volatile phenols Timofeeva, I., Alikina, M., Osmolowsky, M., Osmolovskaya, O., Bulatov, A. New Journal of Chemistry 44(21), с. 8778-8783 https://pubs.rsc.org/en/content/articlelanding/2020/nj/d0nj00854k#!divAbstract IF 3.288, Q1
5. Effect of surfactant coating of Fe₃O₄ nanoparticles on magnetic dispersive micro-solid phase extraction of tetracyclines from human serum Cherkashina, K., Voznesenskiy, M., Osmolovskaya, O., Vakh, C., Bulatov, A. Talanta 214,120861 https://www.sciencedirect.com/science/article/abs/pii/S0039914020301521 IF 5.339, Q1
6. Cobalt-doped hydroxyapatite nanoparticles as a new eco-friendly catalyst of luminol–H₂O₂ based chemiluminescence reaction: Study of key factors, improvement the activity and analytical application Vakh, C., Kuzmin, A., Sadetskaya, A., Bogdanova, P., Voznesenskiy, M., Osmolovskaya, O., Bulatov, A. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 237,118382 https://www.sciencedirect.com/science/article/abs/pii/S1386142520303607?via%3Dihub IF 3.232, Q2
7. Fe₃O₄@HAp core–shell nanoparticles as MRI contrast agent: Synthesis, characterization and theoretical and experimental study of shell impact on magnetic properties Zheltova, V., Vlasova, A., Bobrysheva, N., Abdullin, I., Semenov, V., Osmolowsky, M., Voznesenskiy, Osmolovskaya, O. Applied Surface Science 531,147352 https://www.sciencedirect.com/science/article/abs/pii/S0169433220321097?via%3Dihub IF 6.182, Q1
8. The effect of reaction medium and hydrothermal synthesis conditions on morphological parameters and thermal behavior of calcium phosphate nanoparticles" Evgeniya A. Syukkalova, Anastasia V. Sadetskaya, Natalya D. Demidova, Natalia P. Bobrysheva, Mikhail G. Osmolowsky, Mikhail A. Voznesenskiy, Olga M. Osmolovskaya Ceramics International, In Press, Journal Pre-Proof https://www.sciencedirect.com/science/article/pii/S0272884220328297 IF 3.83, Q1
9. Enhanced visible-light photocatalytic activity of core–shell oxide nanoparticles synthesized by wet chemical precipitation and atomic layer deposition Author links open overlay Anastasiia Podurets, Daniil Kolokolov, Maïss K.S.Barr, Eugenii Ubyivovk, Mikhail Osmolowsky, Natalia Bobrysheva, Julien Bachmann, Olga Osmolovskaya Applied Surface Science, 533, 147520 https://www.sciencedirect.com/science/article/pii/S0169433220322777 IF 6.182, Q1

2019 год

1. Fe₃O₄-based composite magnetic nanoparticles for volatile compound sorption in the gas phase: determination of selenium(iv) Timofeeva, I., Alikina, M., Vlasova, A., Osmolowsky, M., Voznesenskiy, M., Volina, O., Moskvin, L., Osmolovskaya, O., Bulatov, A Analyst 144(1), с. 152-156 https://pubs.rsc.org/en/content/articlelanding/2019/AN/C8AN01894D#!divAbstract IF 3.978, Q1
2. Tin oxide nanoparticles modified by copper as novel catalysts for the luminol-H₂O₂ based chemiluminescence system Vakh, C., Pochivalov, A., Podurets, A., Bobrysheva, N., Osmolovskaya, O., Bulatov, A. Analyst 144(1), с. 148-151 https://pubs.rsc.org/en/content/articlelanding/2019/AN/C8AN01868E#!divAbstract IF 3.978, Q1
3. Effect of capping agents on Co polyol particles morphology, magnetic and catalytic properties Kotelnikova, S.V., Suslonov, V.V., Voznesenskiy, M.A., Bobrysheva, N.P., Osmolowsky, M.G., Rajabi, F., Osmolovskaya, O.M. Materials Chemistry and Physics 223, с. 745-750 https://www.sciencedirect.com/science/article/abs/pii/S0254058418310046?via%3Dihub IF 3.408, Q2
4. Approaches to the Control of Morphological Parameters of Inorganic Nanoparticles in the Synthesis from Solutions Osmolovskaya, O.M., Petukhova, Y.V., Podurets, A.A., Syukkalova, E.A., Suslonov, V.V., Kolokolov, D.S., Kotel’nikova, S.V., Bobrysheva, N.P., Osmolowsky, M.G Russian Journal of General Chemistry 89(6), с. 1154-1161 https://link.springer.com/article/10.1134/S1070363219060094 IF 0.716, Q3
5. Solvent-free preparation of 1,8-dioxo-octahydroxanthenes employing iron oxide nanomaterials Rajabi, F., Abdollahi, M., Diarjani, E.S., Osmolowsky, M.G., Osmolovskaya, O.M., Gómez-López, P., Puente-Santiago, A.R., Luque, R. Materials 12(15),2386 https://www.mdpi.com/1996-1944/12/15/2386 IF 3.057, Q2
6. Polymer composites containing dispersed VO₂ of various polymorphs: Effects of polymer matrix on functional properties Petukhova, Y.V., Kudinova, A.A., Bobrysheva, N.P., Levin, O.V., Osmolowsky, M.G., Osmolovskaya, O.M. Materials Chemistry and Physics 235,121752 https://www.sciencedirect.com/science/article/abs/pii/S0254058419305449?via%3Dihub IF 3.408, Q2