Research group of professor Semenov K.

Department of Solid State Chemistry

Carbon nanomaterials for biomedical application (scientific direction)

Group members

htt Semyonov KN 2020

Leader of direction

Konstantin Semenov

Dr. Sci., Professor

https://orcid.org/0000-0003-2239-2044 

This email address is being protected from spambots. You need JavaScript enabled to view it. | tel. 007-952-2151905| Room 3012
Meshzeryakov Anatoliy Anatolevich

Anatoliy Mescheryakov

PhD student

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Room 3008
Podolskiy Nikita Evgenevich

Nikita Podolsky

PhD student

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Room. 3012
Abdelhalim Abdelsattar Osama Elemam

Abdelhalim Abdelsattar Osama Elemam

PhD student

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Room 3008
Guan Xinyu

Guan Xinyu

PhD student

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комната: 3012
Serebryakov Evgeniy Borisovich

Eugene Serebryakov

PhD student

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Ageev Sergey Vadimovich

Sergei Ageev

Master student

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Shemchuk Olga Sergeevna

Olga Schemchuk

Bachelor student

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Main Directions of Investigations

  1. Synthesis and identification of new substances and materials based on carbon nanostructures:
    1. Synthesis and functionalization of carbon nanostructures (fullerenes, graphenes, nanotubes, nanodiamonds).
    2. Characterization of the obtained substances and materials using modern physicochemical methods: NMR, IR, UV spectroscopy, mass spectrometry, chromatography, thermogravimetry, elemental analysis, microscopy (SEM, TEM, AFM), XPS, Raman spectroscopy, X-ray phase analysis.
  2. Comprehensive physical and chemical study of carbon materials, including the study of the properties of solutions of biologically active substances (density, viscosity, refractive index, electrical conductivity, solubility, activity coefficients, particle size, electrokinetic potential).
  3. Computer modeling of systems containing biologically active substances and materials for biomedical purposes : (Researcher A. Petrov)
    1. Quantum-chemical calculations based on first principles of electronic structure, charge states, equilibrium geometry, NMR, IR and Raman spectra, thermodynamic functions. The absence of empirical parameters in calculations of this kind makes it possible to predict with high accuracy the properties due to the electronic structure.
    2. Calculations of dynamic and structural characteristics by the molecular dynamics method based on ab initio and classical approaches. Determination of diffusion coefficients of molecules, nanoparticles, conjugates for the possible prediction of targeted transmembrane drug delivery into the cell using the mean-square displacements of mobile particles. Prediction of the mechanisms of interaction of new materials with biological fluids based on the analysis of radial distribution functions. Ab initio prediction of molecular dynamics of an adequate picture of the physicochemical reaction associated with the transfer or redistribution of charge in biological systems.

Selected Publications

  1. K. N. Semenov, N. A. Charykov. Temperature dependence of solubility of individual light fullerenes and industrial fullerene mixture in 1-chloronaphthalene and 1-bromonaphthalene // Journal of Chemical and Engineering Data. 2010. V. 55 (7). P. 2373–2378 (Q1, IF=2.290).
  2. K. N. Semenov, N. A. Charykov, V. A. Keskinov, A. K. Piartman, A. A. Blokhin, A. A. Kopyrin. Solubility of light fullerenes in organic solvents // Journal of Chemical and Engineering Data. 2010. V. 55 (1). P. 13–36 (Q1, IF=2.290).
  3. K. N. Semenov, N. A. Charykov, V. A. Keskinov. Fullerenol synthesis and identification. Properties of the fullerenol water solutions // Journal of Chemical and Engineering Data. 2011. V. 56 (2). P. 230–239 (Q1, IF=2.290).
  4. K. N. Semenov, A. S. Kritchenkov, N. A. Charykov. Fullerene bromides C70Brn (n = 8, 10, 14) synthesis and identification and phase equilibria in the C70Brn (n = 8, 10, 14)/solvent systems // Journal of Chemical and Engineering Data. 2013. V. 58 (3). P. 570–575 (Q1, IF=2.290).
  5. K. N. Semenov, A. S. Kritchenkov, I. V. Murin, N. A. Charykov, V. A. Keskinov. Fullerenol-d solubility in fullerenol-d-inorganic salt-water ternary systems at 25°C // Industrial and Engineering Chemistry Research. 2013. V. 52 (46). P. 16095–16100 (Q1, IF=3.375).
  6. A. A. Zolotarev, A. I. Lushin, N. A. Charykov, K. N. Semenov, V. I. Namazbaev, V. A. Keskinov, A. S. Kritchenkov. Impact resistance of cement and gypsum plaster nanomodified by water-soluble fullerenols // Industrial and Engineering Chemistry Research. 2013. V. 52 (41). P. 14583–14591 (Q1, IF=3.375).
  7. A. V. Penkova, S. F. A. Acquah, M. E. Dmitrenko, B. Chen, K. N. Semenov, H. W. Kroto. Transport properties of cross-linked fullerenol-PVA membranes // Carbon. 2014. V. 76. P. 446–450 (Q1, IF=7.466).
  8. K. N. Semenov, N. A. Charykov, I. V. Murin, Y. V. Pukharenko. Physico-chemical properties of the C60-tris-malonic derivative water solutions // Journal of Molecular Liquids. 2015. V. 201. P. 50–58 (Q1, IF=4.561).
  9. K. N. Semenov, N. A. Charykov, I. V. Murin, Y. V. Pukharenko. Physico-chemical properties of the fullerenol-70 water solutions //Journal of Molecular Liquids. 2015. V. 201. P. 1–8 (Q1, IF=4.561).
  10. K. N. Semenov, T. Regueira, J. Fernández, N. A. Charykov, I. V. Murin. Pressure dependence of the solubility of light fullerenes in 1-hexanol from 298.15 K to 363.15 K // Journal of Molecular Liquids. 2015. V. 209. P. 71–76 (Q1, IF=4.561).
  11. O. S. Manyakina, K. N. Semenov, N. A. Charykov, N. M. Ivanova, V. A. Keskinov, V. V. Sharoyko, D. G. Letenko, V. A. Nikitin, V. V. Klepikov, I. V. Murin. Physico-chemical properties of the water-soluble C70-tris-malonic solutions // Journal of Molecular Liquids. 2015. V. 211. P. 487–493(Q1, IF=4.561).
  12. A. A. Shestopalova, K. N. Semenov, N. A. Charykov, V. N. Postnov, N. M. Ivanova, V. V. Sharoyko, V. A. Keskinov, D. G. Letenko, V. A. Nikitin, V. V. Klepikov, I. V. Murin. Physico-chemical properties of the C60-arginine water solutions // Journal of Molecular Liquids. 2015. V. 211. P. 301–307 (Q1, IF=4.561).
  13. N. A. Charykov, V. N. Postnov, V. V. Sharoyko, I. V. Murin. Phase equilibria in fullerene-containing systems as a basis for development of manufacture and application processes for nanocarbon materials // Russian Chemical Reviews. 2016. V. 85 (1). P. 38–59 (Q1, IF=4.612).
  14. K. N. Semenov, N. A. Charykov, V. N. Postnov, V. V. Sharoyko, I. V. Vorotyntsev, M. M. Galagudza, I. V. Murin. Fullerenols: Physicochemical properties and applications // Progress in Solid State Chemistry. 2016. V. 44 (2). P. 59–74 (Q1, IF=6.077).
  15. G. G. Panova, I. N. Ktitorova, O. V. Skobeleva, N. G. Sinjavina, N. A. Charykov, K. N. Semenov. Impact of polyhydroxy fullerene (fullerol or fullerenol) on growth and biophysical characteristics of barley seedlings in favourable and stressful conditions // Plant Growth Regulation. 2016. V. 79. P. 309–317 (Q1, IF=2.473).
  16. K. N. Semenov, N. A. Charykov, G. O. Iurev, N. M. Ivanova, V. A. Keskinov, D. G. Letenko, V. N. Postnov, V. V. Sharoyko, N. A. Kulenova, I. V. Prikhodko, I. V. Murin. Physico-chemical properties of the C60-L-lysine water solutions // Journal of Molecular Liquids. 2017. V. 225. P. 767–777 (Q1, IF=4.561).
  17. K. N. Semenov, A. A. Meshcheriakov, N. A. Charykov, M. E. Dmitrenko, V. A. Keskinov, I. V. Murin, G. G. Panova, V. V. Sharoyko, E. V. Kanash, Yu. V. Khomyakov. Physico-chemical and biological properties of C60-l-hydroxyproline water solutions // RSC Advances. 2017. V. 7. P. 15189–15200 (Q1, IF=3.049).
  18. K. N. Semenov, N. A. Charykov, A. A. Meshcheriakov, E. Lahderanta, A. V. Chaplygin, Yu. A. Anufrikov, I. V. Murin. Physico-chemical properties of the C60-L-threonine water solutions // Journal of Molecular Liquids. 2017. V. 242. P. 740–750 (Q1, IF=4.561).
  19. K. N. Semenov, N. A. Charykov, E. R. López, J. Fernández, V. V. Sharoyko, I. V. Murin. Pressure dependence of the solubility of light fullerenes in n-nonane // Journal of Chemical Thermodynamics. 2017. V. 112. P. 259–266 (Q2, IF=2.290).
  20. B. A. Noskov, K. A. Timoshen, A. V. Akentiev, N. A. Charykov, G. Loglio, R. Miller, K. N. Semenov. Dynamic surface properties of C60-arginine and C60-L-lysine aqueous solutions // Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2017. V. 529, P. 1–6 (Q2, IF=3.131).
  21. M. I. Lelet, K. N. Semenov, E. V. Andrusenko, N. A. Charykov, I. V. Murin. Thermodynamic and thermal properties of the C60-L-lysine derivative // Journal of Chemical Thermodynamics. 2017. V. 115. P. 7–11 (Q2, IF=2.290).
  22. K. N. Semenov, E. V. Andrusenko, N. A. Charykov, E. V. Litasova, G. G. Panova, A.V. Penkova, I. V. Murin, L. B. Piotrovskiy. Carboxylated fullerenes: Physico-chemical properties and potential applications // Progress in Solid State Chemistry. 2017. V. 47–48. P. 19–36 (Q1, IF=6.077).
  23. N. A. Charykov, K. N. Semenov, E. R. López, J. Fernández, E. B. Serebryakov, V. A. Keskinov, I. V. Murin. Excess thermodynamic functions in aqueous systems containing soluble fullerene derivatives // Journal of Molecular Liquids. 2018. V. 256. P. 305–311 (Q1, IF=4.561).
  24. E. B. Serebryakov, K. N. Semenov, I. V. Stepanyuk, N. A. Charykov, A. A. Mescheryakov, A. N. Zhukov, A. V. Chaplygin, I. V. Murin. Physico-chemical properties of the C70-L-lysine aqueous solutions // Journal of Molecular Liquids. 2018. V. 256. P. 507–518 (Q1, IF=4.561).
  25. G. O. Iurev, M. I. Lelet, E. I. Pochkaeva, A. V. Petrov, K. N. Semenov, N. A. Charykov, N. E. Podolsky, L. V. Dulneva, V. V. Sharoyko, I. V. Murin. Thermodynamic and thermal properties of the C60-L-Arg derivative // The Journal of Chemical Thermodynamics. 2018 V. 127. P. 39–44 (Q2, IF=2.290).
  26. K. N. Semenov, N. A. Charykov, E. R. López, J. Fernández, J. J. Parajó, N. E. Podolsky, I. V. Murin. Pressure and temperature dependence of light fullerenes solubility in n-heptane // Journal of Molecular Liquids. 2018. V. 268. P. 569–577 (Q1, IF=4.561).
  27. N. E. Podolsky, M. A. Marcos, D. Cabaleiro, K. N. Semenov, L. Lugo, A. V. Petrov, N. A. Charykov, V. V. Sharoyko, T. D. Vlasov, I. V. Murin. Physico-chemical properties of C60(OH)22–24 water solutions: Density, viscosity, refraction index, isobaric heat capacity and antioxidant activity // Journal of Molecular Liquids. 2019. V. 278. P. 342–355 (Q1, IF=4.561).
  28. E. B. Serebryakov, D. N. Zakusilo, K. N. Semenov, N. A. Charykov, A. V. Akentiev, B. A. Noskov, A. V. Petrov, N. E. Podolsky, A. S. Mazur, L. V. Dul’neva, I. V. Murin. Physico-chemical properties of C70-L-threonine bisadduct (C70(C4H9NO2)2) aqueous solutions // Journal of Molecular Liquids. 2019. V. 279. P. 687–699 (Q1, IF=4.561).
  29. N. E. Podolsky, M. I. Lelet, S. V. Ageev, A. G. Novikov, A. V. Petrov, A. S. Mazur, K. N. Semenov, N. A. Charykov, L. V. Vasina, I. V Murin. Thermodynamic properties from calorimetry and density functional theory and the thermogravimetric analysis of the fullerene derivative C60(OH)40 // Journal of Chemical and Engineering Data. 2019. V. 64 (4). P. 1480–1487 (Q1, IF=2.290).
  30. G. G. Panova, E. B. Serebryakov, K. N. Semenov, N. A. Charykov, O. S. Shemchuk, E. V. Andrusenko, E. V. Kanash, Yu. V. Khomyakov, A. M. Shpanev, L. V. Dulneva, N. E. Podolsky, V. V. Sharoyko. Bioactivity study of the C60-L-threonine derivative for potential application in agriculture // Journal of Nanomaterials. 2019. V. 2019. 2306518 (Q2, IF=2.233).
  31. S. V. Ageev, G. O. Iurev, N. E. Podolsky, I. T. Rakipov, L. V. Vasina, B. A. Noskov, A. V. Akientiev, N. A. Charykov, I. V. Murin, K. N. Semenov. Density, speed of sound, viscosity, refractive index, surface tension and solubility of С60[C(COOH)2]3 // Journal of Molecular Liquids. 2019. V. 291. P. 111256 (Q1, IF=4.561).
  32. N. A. Charykov, M. V. Charykova, K. N. Semenov, V. A. Keskinov, A. V. Kurilenko, Z. K. Shaimardanov, B. K. Shaimardanova. Multiphase open phase processes differential equations // Processes. 2019. V. 7(3). P. 148 (Q2, IF=1.963).
  33. M. A. Marcos, N. E. Podolsky, D. Cabaleiro, L. Lugo, A. O. Zakharov, V. N. Postnov, N. A. Charykov, S. V. Ageev, K. N. Semenov. MWCNT in PEG-400 nanofluids for thermal applications: A chemical, physical and thermal approach // Journal of Molecular Liquids. 2019. V. 294, P. 111616 (Q1, IF=4.561).
  34. D. N. Nikolaev, N. E. Podolsky, M. I. Lelet, N. R. Iamalova, O. S. Shemchuk, S. V. Ageev, A. V. Petrov, K. N. Semenov, N. A. Charykov, L. B. Piotrovskiy, I. V. Murin. Thermodynamic and quantum chemical investigation of the monocarboxylated fullerene C60CHCOOH // Journal of Chemical Thermodynamics. 2020. V. 140, P. 105898 (Q2, IF=2.290).
  35. I. N. Gaponenko, S. V. Ageev, G. O. Iurev, O. S. Shemchuk, A. A. Meshcheriakov, A. V. Petrov, I. L. Solovtsova, L. V. Vasina, T. B. Tennikova, I. V. Murin, K. N. Semenov, V. V. Sharoyko. Biological evaluation and molecular dynamics simulation of water-soluble fullerene derivative C60[C(COOH)2]3 // Toxicology in Vitro. 2020. V. 62, P. 104683 (Q2, IF=3.067).
  36. E. I. Pochkaeva, A. A. Meshcheriakov, S. V. Ageev, N. E. Podolsky, A. V. Petrov, N. A. Charykov, L. V. Vasina, O. Yu. Nikolaeva, I. N. Gaponenko, V. V. Sharoyko, I. V. Murin, K. N. Semenov. Polythermal density and viscosity, nanoparticle size distribution, binding with human serum albumin and radical scavenging activity of the C60-L-arginine (C60(C6H13N4O2)8H8) aqueous solutions // Journal of Molecular Liquids. 2020. V. 297, P. 111915. (Q1, IF=4.561).
  37. E. I. Pochkaeva, N. E. Podolskiy, D. N. Zakusilo, A. V. Petrov, G. G. Panova, K. N. Semenov, N. A. Charykov, T. D. Vlasov, A. V. Penkova, V. V. Sharoyko, I. V. Murin. Fullerene derivatives with amino acids, peptides and proteins: from synthesis to biomedical application // Progress in Solid State Chemistry. 2020. V. 57, P. 100255. (Q1, IF=6.077).
  38. N. E. Podolsky, M. I. Lelet, S. V. Ageev, A. V. Petrov, A. S. Mazur, N. R. Iamalova, D. N. Zakusilo, N. A. Charykov, L. V. Vasina, K. N. Semenov, I. V. Murin. Thermodynamic properties of the C70(OH)12 fullerenol in the temperature range T = 9.2 K to 304.5 K // Journal of Chemical Thermodynamics. 2020. V. 144, P. 106029. (Q2, IF=2,290).
  39. N. P. Bityutskii, K. L. Yakkonen, K. A. Lukina, K. N. Semenov. Fullerenol increases effectiveness of foliar iron fertilization in iron-deficient cucumber // PLoS ONE. 2020, V. 15(5), P. e0232765 (Q1, IF=2.740).
  40. A. V. Akentiev, S. B. Gorniaia, N. A. Isakov, V. T. Lebedev, O. Y. Milyaeva, V. P. Sedov, K. N. Semenov, K. A. Timoshen, B. A. Noskov. Surface properties of fullerenol C60(OH)20 solutions // Journal of Molecular Liquids. 2020. V. 306, P. 112904. (Q1, IF=5.065).
  41. V. V. Sharoyko, S. V. Ageev, A. A. Meshcheriakov, A. V. Akentiev, B. A. Noskov, I. T. Rakipov, N. A. Charykov, N. A. Kulenova, B. K. Shaimardanova, N. E. Podolsky, K. N. Semenov. Physicochemical study of water-soluble C60(OH)24 fullerenol // Journal of Molecular Liquids. 2020. V. 311, P. 113360. (Q1, IF=5.065).
  42. A. O. E. Abdelhalim, V. V. Sharoyko, A. A. Meshcheriakov, M. D. Luttsev, A. A. Potanin, N. R. Iamalova, E. E. Zakharov, S. V. Ageev, A. V. Petrov, L. V. Vasina, I. L. Solovtsova, A. V. Nashchekin, I. V. Murin, K. N. Semenov. Synthesis, characterisation and biocompatibility of graphene–L-methionine nanomaterial // Journal of Molecular Liquids. 2020. V. 314, P. 113605. (Q1, IF=5.065).
  43. N. P. Bityutskii, K. L. Yakkonen, K. A. Lukina, K. N. Semenov, G. G. Panova. Fullerenol can ameliorate iron deficiency in cucumber grown hydroponically // Journal of Plant Growth Regulation. 2020. ASAP (Q1, IF=2.672).
  44. M. A. Marcos, L. Lugo, S. V. Ageev, N. E. Podolsky, D. Cabaleiro, V. N. Postnov, K. N. Semenov. Influence of molecular mass of PEG on rheological behaviour of MWCNT-based nanofluids for thermal energy storage // Journal of Molecular Liquids. 2020. ASAP. (Q1, IF=5.065).
  45. A. O. E. Abdelhalim, V. V. Sharoyko, A. A. Meshcheriakov, S. D. Martynova, S. V. Ageev, G. O. Iurev, H. Al Mulla, A. V. Petrov, I. L. Solovtsova, L. V. Vasina, I. V. Murin, K. N. Semenov. Reduction and functionalisation of graphene oxide with L-cysteine: Synthesis, characterisation and biocompatibility // Nanomedicine: Nanotechnology, Biology and Medicine. 2020. ASAP. (Q1, IF=5.182).
  46. A. A. Meshcheriakov, G. O. Iurev, M. D. Luttsev, N. E. Podolsky, S. V. Ageev, A. V. Petrov, L. V. Vasina, I. L. Solovtsova, V. V. Sharoyko, I. V. Murin, K. N. Semenov. Physicochemical properties, biological activity and biocompatibility of water-soluble C60-Hyp adduct // Colloids and Surfaces B: Biointerfaces. 2020. ASAP (Q1, IF=4.389).

Information for Students

We invite students to our laboratory to carry out coursework and final qualifying works the following areas:

  • Synthesis, identification and physicochemical study of the conjugates of fullerenes with L-amino acids (Dr.Sci., Prof. K.N. Semenov, room 3012. This email address is being protected from spambots. You need JavaScript enabled to view it.)
  • Synthesis and characterisation of conjugates based on graphene oxide, cytostatics and vectors for targeted drug delivery (Dr.Sci., Prof. K.N. Semenov, room 3012. This email address is being protected from spambots. You need JavaScript enabled to view it.)
  • Study the physicochemical, electronic and dynamical properties of superionic conductors for Fluoride-ion battery and carbon materials for medicine. (A. Petrov, Room 3230. This email address is being protected from spambots. You need JavaScript enabled to view it.)