Department of General and Inorganic Chemistry
Solution Chemistry Group
Research team
- Skripkin Mikhail, PhD, Associate Professor — Leader of group. This email address is being protected from spambots. You need JavaScript enabled to view it. ORCID: 0000-0001-9841-150X
- Pestova Olga, PhD, Associate Professor. This email address is being protected from spambots. You need JavaScript enabled to view it. ORCID: 0000-0001-7368-3410
- Khripun Vasily, PhD, Associate Professor. This email address is being protected from spambots. You need JavaScript enabled to view it. ORCID: 0000-0003-0833-3048
- Bogachev Nikita, PhD, Assistant Professor. This email address is being protected from spambots. You need JavaScript enabled to view it. ORCID: 0000-0002-9495-0669
Research collaboration
- Group of Vladimir Sizov, PhD, Associate Professor, Physical Chemistry Dept. — molecular dynamics study of solutions, quantum-chemical description of complex ions in solutions;
- Group of Andrey Mereshchenko, Doctor of Science, Associate Professor, Dept. of Laser Chemistry — photochemistry and photophysics of d-metal complexes in solutions;
- Group of Vladimir Kochemirovskiy, PhD, Associate Professor, Dept. of Laser Chemistry — optimization of compositions for laser-induced formation of metal structures
International contacts
- INE KIT (Institute of Nuclear Waste Disposal, Karlsruhe Institute of Technology) — complexation of lanthanide and actinide ions in solutions
- University of Tehran — synthesis and characterization of metal-organic frameworks (MOFs);
- Institute of Chemical Pharmaceutic, Hungarian Academy of Sciences — vibrational spectroscopic study of complexes;
- University of Enchelada (Мексика) — synthesis of nanostructures from solutions
Current projects
Directed liquid-phase synthesis of metal-organic framework structures and study of the factors of controlling this synthesis. Head of the work – PhD, Associate Professor Mikhail YuryevichSkripkin
Synthesis and study of the properties of metal-organic framework structures is one of the most rapidly developing areas of modern coordination chemistry. It has been established that the formation of these compounds is affected by the nature of organic linkers, the coordination ability of metal centers, the pH value, the duration of the process, temperature, solvent and the ratio of reagents. A number of methods for the synthesis of these substances have been developed, such as the method of slow evaporation, solvothermal, microwave, mechanochemical, etc. An extremely wide range of application of these structures is illustrated - as materials for storing and separating gases (including hydrocarbons), catalytic systems for fine organic synthesis and the synthesis of biologically active substances, luminescent materials. However, such an important aspect as the choice of an appropriate solvent for the synthesis remains not fully understood. The aim of this project is to reveal the effect of solvent on the formation of metal-organic framework structures during hydro/solvothermal synthesis and its influence on the properties of the resulting compounds.
Formation of protective films on titanium alloys used in the primary circuit of light-water nuclear reactors. Supervisor of the work – PhD, Associate Professor Skripkin Mikhail Yurievich.
Structural materials (steels, titanium and zirconium alloys) used in the primary circuit of a nuclear reactor are subject to corrosion due to both chemical (high temperatures and pressures) and radiation effects. The destruction of materials, in particular titanium alloys, is prevented by the formation of protective oxide films on their surface. Despite the fact that the formation of these films has been known for a long time, the mechanism of their formation in the case of titanium alloys remains poorly understood. The goal of this project is to reveal the mechanism of formation of a protective oxide film on the surface of titanium alloys under conditions simulating the primary circuit of a nuclear reactor.
Study of the formation of mixed solvates of transition metal salts in ternary systems containing a mixed solvent or several salts. Supervisor of the work – PhD, Associate Professor Nikita Aleksandrovich Bogachev
The project is aimed to solve the problem of the relationship between the properties of the components of multicomponent solutions, using as the example of three-component systems with competing solvation, and the structure of solid phases crystallizing from them. The main fundamental task of the project is to reveal the influence of the properties and interactions of the components on the formation of the solid phase (solvates) in three-component systems containing several solvents or several salts. This study is at the junction of several relevant and important areas of theoretical and applied chemistry. The goal of this project is to reveal the relationship between the composition of a three-component mixture and the properties of its components and the composition and structure of mixed-ligand and individual solvates crystallizing from such systems.
Study of the relationship between the composition and structure of solid solutions of rare earth and s-element fluorides and their luminescent, magnetic and morphological properties. Supervisor of the research - PhD, Associate Professor Nikita Aleksandrovich Bogachev
Thisproject is carried out within the framework of the RSF 24-73-00034 "Bimodal probes for non-invasive diagnostics of affected tissues based on rare earth fluorides" (supervisor N.A. Bogachev), with collaboration of D.Sc., Associate Professor Andrey SergeevichMereschenko. This project is aimed to studying of nanoparticles of solid solutions of rare earth and s-element fluorides as a polyfunctional inorganic materials that possesses luminescent and magnetic properties, allowing them to be used for non-invasive diagnostics of tissues of living organisms.
To date, the targeted creation of such materials remains a complex task, which is caused by the complex nature of the influence of the synthesis conditions and the composition of such compounds on their functions. The luminescent and magnetic properties of such materials are determined by the type of crystal lattice (the host matrix of luminescent ions), morphology, particle size, the ability of the matrix to form solid substitution solutions with compounds of other lanthanides, including those that do not exhibit luminescent properties. Among the above, the type of crystal structure of the host matrix is the most important factor affecting the optical properties of luminophores, since it determines the symmetry of the environment of such ions, the density of their arrangement in the structure, which affects the mutual spatial arrangement of luminescence centers in the matrix structure. At present, the research is devoted to the study of matrices containing cations of various s-elements.
Study of the structure, micro- and macroproperties of multicomponent water-salt systems. Head of the research - PhD, Associate Professor Pestova O.N.
Electrolyte solutions are complex systems in which many particles can be located under conditions of dynamic equilibrium. Studying the state of ions in solutions, as well as their immediate environment in the case of formation of solvo- and acidocomplexes, allows us to improve model concepts of the structure of solutions, which in turn helps to find patterns in the influence of the microstructure of solutions on the macroproperties of such systems. Studies of the structure of structural zones in solutions, as well as the dependence of their structure on the concentration of the dissolved substance, are of great importance for the development of methods for extracting components from brines, which are used in the chemical technology of salt production. The goal of this project is to study the patterns of formation of the structure of solutions depending on the nature of electrolyte ions and the concentration of substances from the standpoint of the phenomenological model of the structure of aqueous electrolyte solutions on specially selected model systems. The current research areas within this topic are: polythermal study of the cross section of the lithium acetate - cesium acetate - water ternary system; the influence of the nature of the metal on the structure and thermal effects of double lithium chlorides; mobility and immediate environment of particles in lithium acetate – sodium acetate – water mixtures with different ratios of salt components.
Publications
2024
- Complexation of Europium(III) and Terbium(III) Ions with Terephthalic Acid in Aqueous Solutions. Saitov, Y.E., Guseva, P.B., Toikka, Y.N. et al.Russ J Gen Chem., 2024
- Microcrystalline Luminescent (Eu1-xLnx)2bdc3·nH2O (Ln = La, Gd, Lu) Antenna MOFs: Effect of Dopant Content on Structure, Particle Morphology, and Luminescent Properties. Kolesnik, S.S.; Bogachev, N.A.; Kolesnikov, I.E.; Orlov, S.N.; Ryazantsev, M.N.; González, G.; Skripkin, M.Y.; Mereshchenko, A.S.Molecules, 2024
- The Structure and Optical Properties of Luminescent Europium Terephthalate Antenna Metal–Organic Frameworks Doped by Yttrium, Gadolinium, and Lanthanum Ions.Butorlin, O.S.; Petrova, A.S.; Toikka, Y.N.; Kolesnikov, I.E.; Orlov, S.N.; Ryazantsev, M.N.; Bogachev, N.A.; Skripkin, M.Y.; Mereshchenko, A.S. Molecules 2024
- Yulia N. Toikka, Alexander R. Badikov, Nikita A. Bogachev, Ilya E. Kolesnikov, Mikhail Yu. Skripkin, Sergey N. Orlov, Andrey S. Mereshchenko, Luminescent properties and thermal stability of (Lu0.98Eu0.02)2bdc3·10H2O metal–organic frameworks, Mendeleev Communications, Volume 34, Issue 5, 2024, Pages 634-636.
- Alexey A. Dovzhenko, Anna A. Betina, Tatyana S. Bulatova, Nikita A. Bogachev, Vladimir G. Nikiforov, Alexandra D. Voloshina, Rustem R. Zairov, Asya R. Mustafina, Andrey S. Mereshchenko, Bulat S. Akhmadeev, Dual contrasting ability of NaGd0.7Eu0.3F4 nanocrystals tuned by their hydrophilic coating mode, Mendeleev Communications, Volume 34, Issue 5, 2024, Pages 637-639
2023
- Aleksandra Levshakova,Maria Kaneva,Evgenii Borisov, Maxim Panov,AlexandrShmalko,Nikolai Nedelko,Andrey S. Mereshchenko,Mikhail Skripkin,Alina Manshina andEvgeniiaKhairullinaSimultaneous Catechol and Hydroquinone Detection with Laser Fabricated MOF-Derived Cu-CuO@C Composite Electrochemical Sensor. Materials 2023, 16(22), 7225; https://doi.org/10.3390/ma16227225
- Epimakhov, V.N., Orlov, S.N., Mysik, S.G. , Dmitry S. Podshibyakin, Roman V. Fomenkov, Mikhail Yu. Skripkin. Method for iodine radionuclides separation from primary coolant samples. J RadioanalNucl Chem 332, 1767–1774 (2023). https://doi.org/10.1007/s10967-023-08893-6
- Electrochemical Sensors for Controlling Oxygen Content and Corrosion Processes in Lead-Bismuth Eutectic Coolant—State of the Art Orlov, S.N.; Bogachev, N.A.; Mereshchenko, A.S.; Zmitrodan, A.A.; Skripkin, M.Y. Sensors, 2023
- Brightly Luminescent (TbxLu1−x)2bdc3·nH2O MOFs: Effect of Synthesis Conditions on Structure and Luminescent Properties. Nosov, V.G.; Toikka, Y.N.; Petrova, A.S.; Butorlin, O.S.; Kolesnikov, I.E.; Orlov, S.N.; Ryazantsev, M.N.; Kolesnik, S.S.; Bogachev, N.A.; Skripkin, M.Y.; et al. Molecules, 2023
- Effect of Gd3+, La3+, Lu3+ Co-Doping on the Morphology and Luminescent Properties of NaYF4:Sm3+ Phosphors. Nosov, V.G.; Betina, A.A.; Bulatova, T.S.; Guseva, P.B.; Kolesnikov, I.E.; Orlov, S.N.; Panov, M.S.; Ryazantsev, M.N.; Bogachev, N.A.; Skripkin, M.Y.; et al. Materials, 2023
- Complexation of Lanthanide Ions with Citric Acid in Aqueous Solutions. Guseva, P.B., Badikov, A.R., Kadygrob, E.D. et al. Russ J Gen Chem, 2023
- Titanium oxo-hydroxo complexes as precursors of protective oxide films on the surface of titanium alloys in high-temperature water. Pestova, O.N.; Glukhoedov, N.A.; Orlov, S.N.; Mereshchenko, A.S.; Bogachev, N.A.; Skripkin, M.Yu. Int. J. Corros. Scale Inhib., 2023
- Composition and morphology of oxide films formed on PT-7M titanium alloy in high temperature water. Orlov, S.N.; Glukhoedov, N.A.; Zmitrodan, A.A.; Pestova, O.N.; Mereshchenko, A.S.; Bogachev, N.A.; Skripkin, M.Yu. Int. J. Corros. Scale Inhib., 2023
- Morphology and Luminescent Properties of NaYF4 Microcrystalline Up-Conversion Phosphors Doped with Ytterbium(III) and Holmium(III) Ions. Bulatova, T.S., Betina, A.A., Nosov, V.G. et al. Russ J GenChem., 2023
- Morphology and Luminescent Properties of Nanocrystalline NaGdF4 Phosphors Doped with Neodymium(III) Ions. Betina, A.A., Bulatova, T.S., Nosov, V.G. et al. Russ J GenChem., 2023
2022
- Kirill K. Geyl,Sergey V. Baykov,Stanislav A. Kalinin,Alexandr S. Bunev,Marina A. Troshina,Tatiana V. Sharonova,Mikhail Yu. Skripkin,Svetlana O. Kasatkina,Sofia I. Presnukhina,Anton A. Shetnev,Mikhail Yu. Krasavin andVadim P. BoyarskiySynthesis, Structure, and Antiproliferative Action of 2-Pyridyl Urea-Based Cu(II) ComplexesBiomedicines 2022, 10(2), 461; https://doi.org/10.3390/biomedicines10020461
- Nikita A. Glukhoedov,Vitaliy N. Epimakhov,Sergey N. Orlov,Anastasiya A. Tsapko,Aleksandr A. Zmitrodan,Grigoriy A. Zmitrodan andMikhail Yu. SkripkinSorption of 137Cs and 60Co on Titanium Oxide Films in Light Water Reactor Primary Circuit Environment
- Materials 2022, 15(12), 4261; https://doi.org/10.3390/ma15124261
- Lanthanide-Ion-Doping Effect on the Morphology and the Structure of NaYF4:Ln3+ Nanoparticles. Bogachev, N.A.; Betina, A.A.; Bulatova, T.S.; Nosov, V.G.; Kolesnik, S.S.; Tumkin, I.I.; Ryazantsev, M.N.; Skripkin, M.Y.; Mereshchenko, A.S Nanomaterials, 2022
- Heterometallic Europium(III)–Lutetium(III) Terephthalates as Bright Luminescent Antenna MOFs. Nosov, V.G.; Kupryakov, A.S.; Kolesnikov, I.E.; Vidyakina, A.A.; Tumkin, I.I.; Kolesnik, S.S.; Ryazantsev, M.N.; Bogachev, N.A.; Skripkin, M.Y.; Mereshchenko, A.S. Molecules, 2022
- Formation of oxide films on titanium alloys under the conditions of the primary circuit of light-water nuclear reactors (a review) S.N. Orlov, N.A. Bogachev, N.A. Glukhoedov, A.S. Mereshchenko, R.A. Mikailova and M.Yu. Skripkin Int. J. Corros. Scale Inhib., 2022
- Complex Formation of Nickel(II) and Copper(II) Ions with 4,4′-Bipyridine in Non-Aqueous Solvents Bogachev, N.A., Zherebtsova, M.M., Nosov, V.G. et al. Pleiades journals, Russian Journal of General Chemistry, 2022
- Bioorthogonal Paramagnetic Nanocrystalline Phosphor NaGd0.7Eu0.3F4. Bulatova, T.S., Bogachev, N.A., Betina, A.A. et al. Pleiades journals, Russian Journal of General Chemistry, 2022
- Morphology and Luminescent Properties of Microcrystalline NaYF4 Phosphors Doped with Terbium(III) Ions. Betina, A.A., Bulatova, T.S., Kolesnikov, I.E. et al. Pleiades journals, Russian Journal of General Chemistry, 2022
2021
- ValeriiaBaranauskaite,MariaBelysheva,OlgaPestova,YuriAnufrikov,MikhailSkripkin,YuriKondratiev andVassilyKhripun. Thermodynamic Description of Dilution and Dissolution Processes in the MgCl2−CsCl−H2O Ternary System. Materials 2021, 14(14), 4047; https://doi.org/10.3390/ma14144047
- Complex Formation of Cobalt(II) Ions with 4,4′-Bipyridine in Non-Aqueous Solvents Zherebtsova, M.M., Bogachev, N.A., Skripkin, M.Y. et al. Pleiades journals, Russian Journal of General Chemistry, 2021
- Complex Formation of Copper(II) Ions with Phthalate Ions in Non-Aqueous Solvents Bogachev, N.A., Podryadrova, K.A., Skripkin, M.Y. et al. Pleiades journals, Russian Journal of General Chemistry, 2021
- Microcrystalline Anti-Stokes Luminophores NaYF4 Doped with Ytterbium, Erbium, and Lutetium Ions Vidyakina, A.A., Zheglov, D.A., Oleinik, A.V. et al. Pleiades journals, Russian Journal of General Chemistry, 2021
- Dimerization of Phthalate Ion in Non-Aqueous Solvents Nosov, V.G., Podryadrova, K.A., Vasilyeva, M.S. et al. Pleiades journals, Russian Journal of General Chemistry, 2021
- Structures, Bonding and Sensor Properties of Some Alkaline o-PhthalatocupratesGladnev, S.V.; Grigoryev, M.V.; Kryukova, M.A.; Khairullina, E.M.; Tumkin, I.I.; Bogachev, N.A.; Mereshchenko, A.S.; Skripkin, M.Y. Materials, 2021
- Ultrasound-Assisted Synthesis of Luminescent Micro- and Nanocrystalline Eu-Based MOFs as Luminescent Probes for Heavy Metal Ions Kolesnik, S.S.; Nosov, V.G.; Kolesnikov, I.E.; Khairullina, E.M.; Tumkin, I.I.; Vidyakina, A.A.; Sysoeva, A.A.; Ryazantsev, M.N.; Panov, M.S.; Khripun, V.D.; Bogachev, N.A.; Skripkin, M.Y.; Mereshchenko, A.S. Nanomaterials, 2021
- Ultrafast Excited-State Dynamics of CuBr3– Complex Studied with Sub-20 fs ResolutionKhvorost, T. A.; Beliaev, L. Y.; Masaoka, Y.; Hidaka, T.; Myasnikova, O.S.; Ostras, A.S.; Bogachev, N.A.; Skripkin, M.Y.; Panov, M.S.; Ryazantsev, M.N.; Nagasawa, Y.; Mereshchenko, A.S. J. Phys. Chem. B, 2021
- The effect of Eu3+ and Gd3+ co-doping on the morphology and luminescence of NaYF4:Eu3+, Gd3+ phosphors Kolesnikov, I.E.; Vidyakina, A.A.; Vasileva, M.S.; Nosov, V.G.; Bogachev, N.A.; Sosnovsky, V.B.; Skripkin, M.Y.; Tumkin, I.I.; Lähderanta, E.; Mereshchenko, A.S.New J. Chem., 2021
2020
- Study of Tetraethylammonium and Lithium Chlorides Dissociation in Acetonitrile SolutionsVidiakina, AA; Bogachev, NA; Skripkin, MY; Mereshchenko, AS Pleiades journals, Russian Journal of General Chemistry, 2020
- Gd3+-Doping Effect on Upconversion Emission of NaYF4: Yb3+, Er3+/Tm3+ MicroparticlesVidyakina, AA; Kolesnikov, IE; Bogachev, NA; Skripkin, MY; Tumkin, II; Lahderanta, E; Mereshchenko, ASMATERIALS, 2020
- Khvorost, T. A., Beliaev, L. Y., Potalueva, E., Laptenkova, A. V., Selyutin, A. A., Bogachev, N. A., Skripkin, M. Y., Ryazantsev, M. N., Tkachenko, N. &Mereshchenko, A. S., 2020, Journal of Physical Chemistry B. 124, 18, p. 3724-3733 10 p.
2019
- Bogachev, N. A., Gorbunov, A. O., Skripkin, M. Y. &Nikol’skii, A. B., 2019, Russian Journal of General Chemistry. 89, 6, p. 1142-1153
- Skripkin, M. Y., Chernykh, L. V., Pestova, O. N., Baranauskaite, V. E., Burkov, K. A., Zamyatin, I. V., Stepakova, L. V., Gusev, I. M., Gorbunov, A. O., Bogachev, N. A. &Starova, G. L., 2019, Russian Journal of General Chemistry. 89, 6, p. 1085-1101
- Bogachev, N. A., Tsyrul’nikov, N. A., Makarova, A. A., Tolmachev, M. V., Starova, G. L., Skripkin, M. Y. &Nikol’skii, A. B., 2019,Russian Journal of General Chemistry. 89, 5, p. 859-864
- Krapivin, M. A., Ivanov, N. S., Kondratiev, Y. V., Pestova, O. N. &Khripun, V. D., 2019,: Russian Journal of General Chemistry. 89, 4, стр. 856-858
- Baranauskaite, V., Pestova, O., Vovk, M., Matveev, V. &Lähderanta, E., 2019, Physical Chemistry Chemical Physics. 21, 41, стр. 22895-22901 7 стр.