Prikhod'ko Igor Associate Professor This email address is being protected from spambots. You need JavaScript enabled to view it. tel. 007-812-4284066
	Pulyalina Alexandra Associate Professor This email address is being protected from spambots. You need JavaScript enabled to view it.
	Samarov Artemiy Associate Professor This email address is being protected from spambots. You need JavaScript enabled to view it.
	Head of Department Toikka Alexander Doctor of Chemical Sciences, Professor This email address is being protected from spambots. You need JavaScript enabled to view it. tel. 007-812-4284052
	Toikka Maria Associate Professor This email address is being protected from spambots. You need JavaScript enabled to view it.
	Trofimova Maya Associate Professor This email address is being protected from spambots. You need JavaScript enabled to view it. tel. 007-812-4289402
	Zvereva Irina Doctor of Chemical Sciences, Professor This email address is being protected from spambots. You need JavaScript enabled to view it.

Research Staff

	Golikova Alexandra This email address is being protected from spambots. You need JavaScript enabled to view it.
	Silyukov Oleg This email address is being protected from spambots. You need JavaScript enabled to view it.

• Updated in 2023

1. M. Trofimova, A. Sadaev, A. Samarov, A. Golikova, N. Tsvetov, M. Toikka, A. Toikka. Liquid-liquid equilibrium of acetic acid – ethanol – ethyl acetate – water quaternary system: Data review and new results at 323.15 K and 333.15 K. Fluid Phase Equilibria. 2020. V. 503. Article 112321. DOI: 10.1016/j.fluid.2019.112321.
2. D. Gromov, A. Toikka. On an alternative formulation of the thermodynamic stability condition. Journal of Mathematical Chemistry. 2020. V. 58(6). P. 1219-1229. DOI: 10.1007/s10910-020-01126-1
3. A.V. Petrov, A.M. Toikka. Charge States of Sorption Centers in Matrimid. Glass Physics and Chemistry. 2020. V. 46(2). P. 186-188. DOI: 10.1134/S1087659620020091
4. A. Golikova, N. Tsvetov, A. Samarov, M. Toikka, I. Zvereva, M. Trofimova, A. Toikka. Excess enthalpies and heat of esterification reaction in ethanol + acetic acid + ethyl acetate + water system at 313.15 K. Journal of Thermal Analysis and Calorimetry. 2020. V. 139. P. 1301–1307. DOI:10.1007/s10973-019-08488-yvo
5. M. Farzaneh‑Gord, H. R. Rahbari, B. Mohseni‑Gharyehsafa, A. Toikka, I. Zvereva. Machine learning methods for precise calculation of temperature drop during a throttling process. J. Therm. Analysis and Calorimetry. 2020. V. 140(6). P. 2765-2778. DOI: 10.1007/s10973-019-09029-3
6. A. Samarov, M. Trofimova, M. Toikka, A. Toikka. Experimental Data on Chemical Equilibrium in the System with Ethyl Formate Synthesis Reaction at 298.15 K. Journal of Chemical and Engineering Data. 2020. V. 65. Issue 5. P. 2578-2582. DOI: 10.1021/acs.jced.9b01205
7. V. V. Voytovich, S. A. Kurnosenko, O. I. Silyukov, I. A. Rodionov, I. A. Minich, I. A. Zvereva. Study of N-Alkylamine Intercalated Layered Perovskite-Like Niobates HCa₂Nb₃O₁₀ as Photocatalysts for Hydrogen Production From an Aqueous Solution of Methanol. Frontiers in Chemistry. 2020. 8. 300.
8. I. A. Minich, O. I. Silyukov, V. V. Gak, E. V. Borisov, I. A. Zvereva. Synthesis of Organic−Inorganic Hybrids Based on Perovskite-like Bismuth Titanate H₂K₀.₅Bi₂.₅Ti₄O₁₃·H₂O and n‑Alkylamines. ACS Omega 2020. 5. P. 8158−8168.
9. A. M. Sankovich, T. D. Myshkovskaia, A. V. Markin, N.N. Smirnova, I. A. Zvereva. Isobaric heat capacity and standard thermodynamic properties of cationordered layered perovskite-like oxides NaLnTiO₄ and A₂Ln₂Ti₃O₁₀ (A=H, Na, K; Ln=La, Nd, Gd). Thermochimica Acta. 2020. 686. 178533
10. T. A. Kryuchkova, V. V. Kost’, T. F. Sheshko, I. V. Chislova, L. V. Yafarova, and I. A. Zvereva, Effect of Cobalt in GdFeO₃ Catalyst Systems on Their Activity in the Dry Reforming of Methane to Synthesis Gas. Petroleum Chemistry. 2020. 60(5). P. 609–615.
11. T. Sheshko, A. Sharaeva, O. Powella, Yu. Serov, I. Chislova, L. Yafarova, A. Koroleva, I. Zvereva, Carbon Oxide Hydrogenation over GdBO₃ (B = Fe, Mn, Co) Complex Oxides: Effect of Carbon Dioxide on Product Composition. Petroleum Chemistry. 2020. V. 5. P. 17–23.
12. M. G. Shelyapina, I. P. Lushpinskaya, S. A. Kurnosenko, O. I. Silyukov, and I. A. Zvereva. Identification of Intercalates and Grafted Organic Derivatives of H₂La₂Ti₃O₁₀ by Multinuclear NMR. Russian Journal of General Chemistry. 2020. 90(4). P. 760-761.
13. A. Pulyalina, I. Faykov, V. Nesterova, M. Goikhman, I. Podeshvo, N. Loretsyan, A. Novikov, I. Gofman, A. Toikka, G. Polotskaya. Novel Polyester Amide Membranes Containing Biquinoline Units and Complex with Cu(I): Synthesis, Characterization, and Approbation for n-Heptane Isolation from Organic Mixtures. Polymers. 2020. 12. Article 645. doi:10.3390/polym12030645
14. N. Tsvetov, A. Sadaeva, M. Toikka, A. Toikka. Excess molar heat capacity for the binary system n-propyl alcohol + water in the temperature range 278.15–358.15 K: new data and application for excess enthalpy calculation. Journal of Thermal Analysis and Calorimetry. 2020. DOI: 10.1007/s10973-020-09605-y
15. I. A. Rodionov, E. A. Maksimova, A. Y. Pozhidaev, S. A. Kurnosenko, O.I. Silyukov, I. A. Zvereva. Layered Titanate H₂Nd₂Ti₃O₁₀ Intercalated with n-Butylamine: a New Highly Efficient Hybrid Photocatalyst for Hydrogen Production from Alcohol Solutions. Frontiers in Chemistry. 2019. V. 7. Article 863.
16. I. A. Minich, O. I. Silyukov, L. D. Kulish, I. A. Zvereva. Study on thermolysis process of a new hydrated and protonated perovskite-like oxides H₂K₀.₅Bi₂.₅Ti₄O₁₃·H₂O. Ceramics International. 2019. 45(2). P. 2704-2709.
17. A. Pulyalina, V. Rostovtseva, G. Polotskaya, L. Vinogradova, Z. Zoolshoev, M. Simonova, A. Hairullin, A. Toikka, Z. Pientka. Hybrid macromolecular stars incorporated poly(phenylene oxide) membranes: Organization, physical, and gas separation properties. Polymer. 2019. V. 172. P. 355–364. DOI: 10.1016/j.polymer.2019.04.005
18. G. Polotskaya, A. Pulyalina, M. Goikhman, I. Podeshvo, I. Gofman, S. Shugurov, V. Rostovtseva, I. Faykov, M. Tataurov, A. Toikka, A. Polotsky. Asymmetric Membranes Based on Copolyheteroarylenes with Imide, Biquinoline, and Oxazinone Units: Formation and Characterization. Polymers. 2019. V. 11. Article 1542. DOI: 10.3390/polym11101542
19. A. Samarov, N. Shner, E. Mozheeva, A. Toikka. Liquid-liquid equilibrium of alcohol–ester systems with deep eutectic solvent on the base of choline chloride. The Journal of Chemical Thermodynamics. 2019. V. 131. P. 369–374. DOI: 10.1016/j.jct.2018.11.019
20. M. Trofimova, A. Sadaev, A. Samarov, M. Toikka, A. Toikka. Solubility, liquid-liquid equilibrium and critical states for the quaternary system formic acid – ethanol – ethyl formate – water at 298.15 K and 308.15 K. Fluid Phase Equilibria. 2019. V. 485. P. 111-119. DOI: 10.1016/j.fluid.2018.12.024
21. M. Toikka, A. Sadaeva, A. Samarov, A. Toikka. Solubility and critical surface in the system propionic acid – ethanol – ethyl propionate – water at 293.15, 303.15 and 313.15 K. The Journal of Chemical Thermodynamics. 2019. V. 132. P. 113–121. DOI: 0.1016/j.jct.2018.12.026
22. I. V. Prikhod’ko, A. A. Samarov, A. M. Toikka. On Application of PC–SAFT Model for Estimating the Speed of Sound in Synthetic and Natural Oil-and-Gas Mixtures. Russian Journal of Applied Chemistry. 2019. V. 92. No. 2. P. 262−266. DOI: 10.1134/S1070427219020150
23. A. M. Toikka, A. A. Samarov, M. Farzaneh-Gord, I. A. Zvereva. On Calculation of Some Properties of Natural Gas Using a Limited Number of Experimental Parameters. Theoretical Foundations of Chemical Engineering. 2019. V. 53. No. 1. P. 21–28. DOI: 0.1134/S0040579519010159
24. A. Samarov, I. Prikhodko, N. Shner, G. Sadowski, C. Held, A. Toikka. Liquid−Liquid Equilibria for Separation of Alcohols from Esters Using Deep Eutectic Solvents Based on Choline Chloride: Experimental Study and Thermodynamic Modeling. J. Chem. Eng. Data. 2019. V. 64. Issue 12. P. 6049-6059. DOI: 10.1021/acs.jced.9b00884
25. A.V. Petrov, M.A. Smirnov, M.P. Sokolova, A.M. Toikka. Influence of Water Concentration on Its Mobility in Matrimid®. Coatings. 2019. V. 9. Article 466. DOI:10.3390/coatings9080466
26. L.V. Yafarova, I.V. Chislova, I.A. Zvereva, T.A. Kryuchkova, T.F. Shehko. Sol-gel synthesis and investigation of catalysts on the basis of perovskite-type oxides GdMO₃ (M= Fe, Co). Journal of Sol-Gel Science and Technology. 2019. V. 92. P. 264-272.
27. A.M. Sankovich, A.V. Markin, N.N. Smirnova, I.A. Zvereva. Heat Capacity and the Thermodynamic Properties of Layered Perovskite-Like Oxides K₂La₂Ti₃O₁₀ and K₂Nd₂Ti₃O₁₀. Russian Journal of Physical Chemistry A. 2019. V. 93. № 3. P.407–416.
28. M. G. Shelyapina, D. Nefedov, A. V. Kostromin, O. I. Silyukov, I. A. Zvereva. Proton mobility in Ruddlesden−Popper phase Н₂La₂Ti₃O₁₀ studied by 1H NMR. Ceramics International. 2019. 45(5). P. 5788-5795.
29. V. A. Vorozhtcov , V. L. Stolyarova , M. V. Chislov , I. A. Zvereva , E. P. Simonenko , N. P. Simonenko. Thermodynamic properties of lanthanum, neodymium, gadolinium hafnates (Ln₂Hf₂O₇): Calorimetric and KEMS studies. Journal of Materials Research. 2019. V. 34. P. 3326-3336
30. S. I. Niftaliev. I.V. Kuznetsova, I. Saranov, T. V. Zhundrikova, L. V. Lygina, V. Yu. Tuneekov, I. V. Chislova, I. A. Zvereva. Synthesis of Nanosized Gadolinium Oxide Glass Physics and Chemistry. 2019. 45(3). P. 232-237.
31. D. P. Kiryukhin, A.S. Bespalov, V. M. Bouznik, D. V. Grashchenkov,V. K. Ivanov,I. A. Zvereva, G. A. Kichigina, P. P. Kushch.Application of Low-Temperature Postradiation Polymerization of Polytetrafluoroethylene for Hydrophobization of Porous Ceramic Materials Based on Oxide Fibers. Inorganic Materials Applied Research, 2019. V. 10. № 2. Р. 467–472.
32. I.A. Zvereva, V.M. Kuznetsov, Yu.M. Zhukov, A.N. Mazurkevich, E.V. Dolbunova. Thermal analysis and multi-analytical comparison of samples of Neolithic ceramics from Dnepr–Dvina and Low Don regions. Journal of Thermal Analysis and Calorimetry 2019. V. 138. N3. P. 1879–1886
33. A.A. Petrov, S.A. Fateev, Y,V. Zubavichus, P.V. Dorovatovskii,V.N. Khrustalev, I. A. Zvereva, A.V. Petrov, E.A. Goodilin, A.B. Tarasov. Methylammonium Polyiodides: Remarkable Phase Diversity of the Simplest and Low-Melting Alkylammonium Polyiodide System. The Journal of Physical Chemistry Letters. 2019. 10. 19. P. 5776-5780.
34. T.F. Sheshko, E.B.Markova, A.A. Sharaeva, T.A. Kryuchkova, I.A. Zvereva, I.V. Chislova, L.V. Yafarova. Carbon Monoxide Hydrogenation over Gd(Fe/Mn)O₃ Perovskite-Type Catalysts. Petroleum Chemistry. 2019. 59(12). P. 1307-1313
35. T.F. Sheshko, T.A. Kryuchkova, A.A. Sharaeva, Y.M. Serov, L.V. Yafarova, I.A. Zvereva. The performance evaluation of nanostructured perovskite-type complex oxides GdBO₃ (B = Fe, Co, Mn) for carbon monoxide hydrogenation. Journal of Physics: Conference Series. 2019. 1310(1). Article 012007.
36. A. Yu. Pulyalina, M. N. Putintseva, G. A. Polotskaya, V. A. Rostovtseva, A. M. Toikka. Pervaporation Purification of Oxygenate from an Ethyl tert-Butyl Ether/Ethanol Azeotropic Mixture. Membranes and Membrane Technologies. 2019. V. 1. No. 2. P. 99–106.
37. A.M. Sankovich, A.V. Markin, N.N. Smirnova, M.D. Bal’makov, I.A. Zvereva. Isobaric heat capacity and standard thermodynamic properties of NaLaTiO4 and Na₂La₂Ti₃O₁₀ over the range of (7 to 670) K. Journal of Thermal Analysis and Calorimetry. 2018. 131(2). P. 1107–1114
38. T. Utkina, М. Chislov, M. Myshenkov, I. Rodionov, I. Zvereva. Water sorption by the perovskite-like layered titanate K₂Nd₂Ti₃O₁₀ in humid atmosphe. Journal of Thermal Analysis and Calorimetry. 2018. 34(1). P. 323–331. DOI:10.1007/s10973-018-7017-1
39. M. Shelyapina, I. Zvereva, L. Yafarova, D. Bogdanov, S. Sukharzhevskii, Yu. Zhukov. V .Petranovskii. Thermal analysis and EPR study of copper species in mordenites prepared by conventional and microwave-assisted methods. Journal of Thermal Analysis and Calorimetry. 2018. 34(1). P. 71-79. DOI:10.1007/s10973-018-7016-2
40. O.I. Silyukov, I.A. Minich, I.A. Zvereva. Synthesis of Protonated Derivatives of Layered Perovskite-Like Bismuth Titanates. Glass Physics and Chemistry. 2018. V. 44. № 2. P. 115–119.
41. O.I. Silyukov, S. A. Kurnosenko, I. A. Zvereva. Intercalation of Methylamine into the Protonated Forms of Layered Perovskite-Like Oxides HLnTiO₄ (Ln = La and Nd). Glass Physics and Chemistry. 2018. 44(5). P. 428-432.
42. A. M. Kalinkin, B. I. Gurevich, M. S. Myshenkov, E. V. Kalinkina, I. A. Zvereva. A calorimetric study of hydration of magnesia-ferriferous slag mechanically activated in air and in CO₂ atmosphere. Journal of Thermal Analysis and Calorimetry. 2018. 134(1). P.165–171.
43. A. M. Kalinkin, A. V. Usol’tsev, E. V. Kalinkina, M. V. Chislov, I. A. Zvereva, V. N. Nevedomskii. Synthesis of La₂Zr₂O₇ by thermal treatment of mechanically activated salt mixture. Journal of Thermal Analysis and Calorimetry. 2018. 134(1). P. 111–118.
44. I.A. Zvereva, E.A.Tugova, V.F. Popova, O.I. Silyukov, I.A. Minich. The impact of substitution Nd3+/La3+on the cation distribution and phase diagram in the system La2SrAl2O7-Nd2SrAl2O7. Chimica Techno Acta. 2018. V. 5. № 1. P. 80-85.
45. A.Toikka, On non-equilibrium thermodynamics approach for the analysis of membrane processes: a case study of pervaporation, Monatshefte fur Chemie. 2018. V. 149. Issue 2. P. 467-473. DOI: 10.1007/s10973-018-7110-5
46. N.Tsvetov, I.Letyanina, I.Zvereva, A.Toikka, Excess molar enthalpies of the ternary mixture n-propanol + n-propyl acetate + water at 313.15 K, Journal of Thermal Analysis and Calorimetry. 2018. 133(2). P. 1149-1156. DOI: 10.1007/s10973-018-7110-5
47. N.Avagimova, G.Polotskaya, A.Toikka, A.Pulyalina, Z.Moravkova, M.Trchova, Z.Pientka, Effect of nanodiamond additives on the structure and gas-transport properties of a poly(phenylene–isophtalamide) matrix, Journal of Applied Polymer Science. 2018. V. 135. Issue 23. P. 46320. DOI: 10.1002/app.46320
48. A. Golikova, N. Tsvetov, Yu. Anufrikov, M. Toikka, I. Zvereva, A.M. Toikka, Excess enthalpies of the reactive system ethanol + acetic acid + ethyl acetate + water for chemically equilibrium states at 313.15 K, Journal of Thermal Analysis and Calorimetry. 2018. 134(1). P. 835-841. DOI: 10.1007/s10973-018-7010-8
49. E.A. Krylova, M.G. Shelyapina, P. Nowak, H. Harańczyk, M. Chislov, I.A. Zvereva, A.F. Privalov, M. Vogel, V. Petranovskii. Mobility of water molecules in sodium- and copper-exchanged mordenites: Thermal analysis and 1H NMR study. Microporous &Mesoporous Materials. 2018. V. 265. P. 132-142. DOI:10.1016/j.micromeso.2018.02.010
50. I.A. Rodionov, E.V. Mechtaeva, A.A.Burovikhina, O.I. Silyukov, M.A. Toikka, I.A. Zvereva. Effect of protonation on the photocatalytic activity of the K2La2Ti3O10 layered oxide in the reaction of hydrogen production. Monatshefte für Chemie - Chemical Monthly. 2018, V. 149. Issue 2. P. 475–482. DOI:10.1007/s00706-017-2105-7
51. A.E. Musikhin, V.N. Naumov, M.V. Chislov, I.A. Zvereva. Thermodynamic properties of CaMoO4 at high temperatures. Thermochimica Acta. 2018. V. 661. P. 160–165. DOI:10.1016/j.tca.2018.01.023
52. Y.M. Zhukov, M.G. Shelyapina, I.A. Zvereva, A.Yu. Efimov, V. Petranovskii. Microwave assisted versus convention Cu2+ exchange in mordenite. Microporous and Mesoporous Materials. 2018. V. 259, P. 220-228. DOI:10.1016/j.micromeso.2017.10.013
53. O.I. Silyukov, L.D. Kulish, D.V. Trofimova, A.A.Burovikhina, M.V. Chislov, I.A. Rodionov, Yu.M. Zhukov, I.A. Zvereva. Formation of vanadium-containing nanostructures on the surface of protonated forms of layered perovskite-like titanates K2La2Ti3O10 and NaLaTiO4. Journal of Solid State Chemistry. 2018, V. 259, P. 28–34. DOI:10.1016/j.jssc.2017.12.032
54. A.A. Samarov, M.A. Smirnov, A.M. Toikka, I.V. Prikhodko. Study of Deep Eutectic Solvent on the Base Choline Chloride as Entrainer for the Separation Alcohol–Ester Systems. Journal of Chemical and Engineering Data. 2018. 63(6). P. 1877-1884 DOI: 10.1021/acs.jced.7b00912
55. M. Toikka, V. Vernadskaya, A. Samarov. Solubility, liquid-liquid equilibrium and critical states for quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water at 303.15 K and atmospheric pressure. Fluid Phase Equilibria. 2018. V. 471. P. 68-73. DOI:10.1016/j.fluid.2018.05.009
56. M. Toikka, D. Trofimova, A. Samarov. Liquid-liquid equilibrium and critical states for the quaternary system propionic acid-n-butanol-n-butyl propionate-water at 303.15 K. Fluid Phase Equilibria. 2018. V. 460, P. 17-22. DOI:10.1016/j.fluid.2017.12.023
57. A.A. Samarov, M.A. Smirnov, M.P. Sokolova, A.M. Toikka. Liquid-Liquid Equilibrium Data for the System N-Octane + Toluene + DES at 293.15 and 313.15 K and Atmospheric Pressure. Theoretical Foundations of Chemical Engineering. 2018. V. 52. Issue 2. P. 258-263. DOI:10.1134/S0040579518020148

Founders of Chemical Thermodynamics Scientific School of St. Petersburg State University

• Prof. Konovalov Dmitriy Petrovich (1878-1907 at the University), regular member (academician) of the Russian Academy of Sciences (RAS) (1923)
• Prof. Vrevskiy Mihail Stepanovich (1890-1929 at the University), Corresp. Member of the RAS (1929).
• Prof. Storonkin Aleksey Vasil'evich (1935-1994 at the University), founder and Head of the Department of the Theory of Solutions (1951, in 1978 renamed as Department of Chemical Thermodynamics & Kinetics), Dr. Sci. (Chemistry), Emeritus Person in Science and Engineering of the Russian Federation, State Scientific Prize winner (1951). Among his students: Prof. A.I.Rusanov and Prof. M.M.Shultz, academicians of the Russian Academy of Science, Prof. N.A.Smirnova, corresponding member of the RAS, Professors V.K.Filippov, N.P.Markuzin, A.G.Morachevskiy, M.P.Susarev, V.T.Zharov.

Principal publications of the founders of the Chemical Thermodynamics Scientific School

• Konovalov D.P. On the Vapor Pressure of Solutions, Leningrad, 1928.
• Vrevskii M.S. Papers on the Theory of Solutions, Moscow-Leningrad, 1953.
• Storonkin A.V. On Thermodynamic Equilibrium of Multicomponent Systems, Leningrad, 1948.
• Storonkin A.V. Thermodynamics of Heterogeneous Systems, Leningrad, P. 1-2, 1967; P. 3, 1969.

General Fields of Research Projects

• Membrane processes, polymer nanocomposites, pervaporation, polymeric membranes
• Reactive mass-exchange processes, heterogeneous equilibria and critical phenomena in multicomponent reaction systems
• Solid-phase reactions, photocatalytic processes, nanostructured inorganic and hybrid organic-inorganic materials

Research Projects

Department Members

Selected Publications of ChTK Department 2018–2020

History of the Department