Department of Analytical chemistry, Laboratory 3131
Sample Preparation Methods Scientific Group
Staff
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Prof. Andrey V. BulatovDoctor of Science, Professor of Russian Academy of Sciences, Professor St. Petersburg State University, Institute of Chemistry, Universitetskiy pr., 26, 198504, Saint-Petersburg, Russia This email address is being protected from spambots. You need JavaScript enabled to view it. |
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Christina VakhPhD, Assistant Professor This email address is being protected from spambots. You need JavaScript enabled to view it. |
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Irina TimofeevaPhD, Assistant Professor This email address is being protected from spambots. You need JavaScript enabled to view it. |
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Andrey ShishovPhD, Assistant Professor This email address is being protected from spambots. You need JavaScript enabled to view it. |
Students
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Kseniia CherkashinaPostgraduate student, 3 year |
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Aleksei PochivalovPostgraduate student, 3 year |
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Sofia LebedynetsPostgraduate student, 1 year |
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Firuza ShakirovaPostgraduate student, 1 year |
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Kira StepanovaMaster student, 2 year |
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Natalya VolodinaMaster student, 2 year |
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Polina BogdanovaMaster student, 2 year |
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Marina ZhdanovaMaster student, 1 year |
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Svetlana KasperMaster student, 1 year |
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Pavel TernoBachelor student, 4 year |
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Artur GerasimovBachelor student, 4 year |
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Ivan GuryevBachelor student, 3 year |
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Ivan DubrovskyBachelor student, 3 year |
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Maria KochetkovaBachelor student, 3 year |
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Kseniia MalkovaBachelor student, 3 year |
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Anna PonomarevaBachelor student, 3 year |
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Elizaveta UsikovaBachelor student, 2 year |
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Egor NizovBachelor student, 2 year |
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Maria MelesovaBachelor student, 2 year |
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Ulyana MarkovaBachelor student, 2 year |
Collaboration with Russian and international groups
- Prof. V. Andruch, Pavol Jozef Šafárik, University in Košice, Slovakia
- Prof. S. Garmonov, Kazan National Research Technological University
Fields of scientific interests
Fields of scientific interests are microextraction methods for the separation and preconcentration of various analytes from complex samples (human fluids, food products, pharmaceuticals, oil products). Particular attention is paid to "designer" extraction systems based on the formation of deep eutectic solvents and supramolecular systems. Research is also carried out in the field of automation of microextraction processes based on the flow methods and their combination with other analytical instrumentations.
Publications
2020
- I. Timofeeva, K. Stepanova, A. Shishov, L. Nugbienyo, L. Moskvin, A. Bulatov. Fluoroquinolones extraction from meat samples based on deep eutectic solvent formation. Journal of Food Composition and Analysis. 93 (2020)103589. DOI:10.1016/j.jfca.2020.103589
- A. Shishov, A. Gorbunov, E. Baranovskii, A. Bulatov, Microextraction of sulfonamides from chicken meat samples in three-component deep eutectic solvent, Microchem. J. 158 (2020) 105274. DOI: 10.1016/j.microc.2020.105274.
- A. Shishov, A. Pochivalov, L. Nugbienyo, V. Andruch, A. Bulatov. Deep eutectic solvents are not only effective extractants, Trends Anal. Chem. 2020. DOI: 10.1016/j.trac.2020.115956.
- I. Timofeeva, M. Alikina, M. Osmolowsky, O. Osmolovskaya, A. Bulatov. Magnetic headspace adsorptive microextraction using Fe3O4@Cr(OH)3 nanoparticles for effective determination of volatile phenols. New Journal of Chemistry. 2020. DOI: 10.1039/D0NJ00854K
- C. Vakh, A. Kuzmin, A. Sadetskaya, P. Bogdanova, M. Voznesenskiy, O. Osmolovskaya, A.Bulatov. Cobalt-doped hydroxyapatite nanoparticles as a new eco-friendly catalyst of luminol-H2O2 based chemiluminescence reaction: study of key factors, improvement the activity and analytical application. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2020. DOI: 10.1016/j.saa.2020.118382
- P. Bogdanova, A. Pochivalov, C. Vakh, A. Bulatov. Supramolecular solvents formation in aqueous solutions containing primary amine and monoterpenoid compound: Liquid phase microextraction of sulfonamides. Talanta. 2020. DOI: 10.1016/j.talanta.2020.120992
- A. Shishov, A. Gerasimov, D. Nechaeva, N. Volodina, E. Bessonova, A. Bulatov. An effervescence-assisted dispersive liquid-liquid microextraction based on deep eutectic solvent decomposition: determination of ketoprofen and diclofenac in liver. 2020. DOI: 10.1016/j.microc.2020.104837
- D. Kanashina, A. Pochivalov, I. Timofeeva, A. Bulatov. Mixed surfactant systems based on primary amine and medium-chain fatty acid: Micelle-mediated microextraction of pesticides followed by the GC–MS determination. Journal of Molecular Liquids, 306 (2020) 112906. DOI: 10.1016/j.molliq.2020.112906
- K. Cherkashina, M. Voznesenskiy, O. Osmolovskaya, C. Vakh, A. Bulatov. Effect of surfactant coating of Fe3O4 nanoparticles on magnetic dispersive micro-solid phase extraction of tetracyclines from human serum. Talanta. 2020. DOI: 10.1016/j.talanta.2020.120861.
- A. Shishov, S. Gagarionova, A. Bulatov. Deep eutectic mixture membrane-based microextraction: HPLC-FLD determination of phenols in smoked food samples. Food Chemistry. 2020. DOI: 10.1016/j.foodchem.2019.126097
2019
- S. Lebedinets, C. Vakh, K. Cherkashina, A. Pochivalov, L. Moskvin, A. Bulatov. Stir membrane liquid phase microextraction of tetracyclines using switchable hydrophilicity solvents followed by high-performance liquid chromatography. Journal of Chromatography A. 2019. DOI: 10.1016/j.chroma.2019.460743
- A. Shishov, A. Gorbunov, L. Moskvin, A. Bulatov. Decomposition of deep eutectic solvents based on choline chloride and phenol in aqueous phase. Journal of Molecular Liquids. 2019. DOI: 10.1016/j.molliq.2019.112380
- A. Pochivalov, C. Vakh, S. Garmonov, L. Moskvin, A. Bulatov. An automated in-syringe switchable hydrophilicity solvent-based microextraction. Talanta. 2019. DOI: 10.1016/j.talanta.2019.120587
- С. Vakh, I. Timofeeva, A. Bulatov. Automation of Microextraction Preconcentration Methods Based on Stepwise Injection Analysis Journal of Analytical Chemistry. 2019. DOI: 10.1134/S106193481911011X
- A.Shishov, E.Stolarova, L.Moskvin, A.Bulatov. Reversed-phase chromatomembrane extraction as a novel approach for automated sample pretreatment: Anions determination in biodiesel by ion chromatography with conductivity detection. Analytica Chimica Acta. 2019. DOI:10.1016/j.aca.2019.08.031.
- A.Shishov, P.Terno, L.Moskvin, A.Bulatov. In-syringe dispersive liquid-liquid microextraction using deep eutectic solvent as disperser: Determination of chromium (VI) in beverages. Talanta. 2020. DOI:10.1016/j.talanta.2019.120209.
- A.Shishov, I.Trufanov, D. Nechaeva, A. Bulatov. A reversed-phase air-assisted dispersive liquid-liquid microextraction coupled with colorimetric paper-based analytical device for the determination of glycerol, calcium and magnesium in biodiesel samples. Microchemical Journal. 2019. DOI:10.1016/j.microc.2019.104134.
- A. Shishov, D. Nechaeva, A. Bulatov. HPLC-MS/MS determination of non-steroidal anti-inflammatory drugs in bovine milk based on simultaneous deep eutectic solvents formation and its solidification. Microchemical Journal. 2019. DOI: 10.1016/j.microc.2019.104080.
- K. Cherkashina, S. Lebedinets, A. Pochivalov, A. Lezov, C. Vakh, A. Bulatov. Homogeneous liquid-liquid microextraction based on primary amine phase separation: a novel approach for sample pretreatment. Analytica Chimica Acta. 2019. DOI: 10.1016/j.aca.2019.04.070.
- I.Timofeeva, D. Kanashina, K. Stepanova, A. Bulatov. A simple and highly-available microextraction of benzoic and sorbic acids in beverages and soy sauce samples for high performance liquid chromatography with ultraviolet detection. Journal of Chromatography A. 2019. DOI: 10.1016/j.chroma.2018.12.030.
- A. Shishov, R. Chromá, C. Vakh, J. Kuchár, A. Simon, V. Andruch, A. Bulatov. In situ decomposition of deep eutectic solvent as a novel approach in liquid-liquid microextraction. Analytica Chimica Acta. 2019. DOI:10.1016/J.ACA.2019.03.038.
- A. Bulatov, L. Moskvin, O. Rodinkov, S. Ermakov, Department of Analytical Chemistry of Saint Petersburg State University Celebrates One Hundred and Fifty Years Anniversary: International Year of the Periodic Table of Chemical Elements. Talanta. 2019. DOI: 10.1016/j.talanta.2019.03.081
- Christina Vakh, Marcel Alaboud, Sofya Lebedinets, Andrey Bulatov. A rotating cotton-based disk packed with a cation-exchange resin: Separation of ofloxacin from biological fluids followed by chemiluminescence determination. Talanta. 2019. V. 196. P. 117-123. DOI: 10.1016/j.talanta.2018.12.024
- Irina Timofeeva, Mariya Alikina, Anna Vlasova, Mikhail Osmolowsky, Mikhail Voznesenskiy, Olga Volina, Leonid Moskvin, Olga Osmolovskaya, Andrey Bulatov. Fe3O4-based composite magnetic nanoparticles for volatile compound sorption in gas phase: determination of selenium (IV). Analyst. 2019. V. 144. P. 152 - 156. DOI: 10.1039/C8AN01894D
2018
- Christina Vakh, Aleksei Pochivalov, Anastasiia Podurets, Natalia Bobrysheva, Olga Osmolovskaya and Andrey Bulatov. Tin oxide nanoparticles modified by copper as novel catalysts for the luminol–H2O2 based chemiluminescence system. Analyst. 2018. DOI: 10.1039/C8AN01868E
- Andrey Shishov, Natalia Volodina, Daria Nechaeva, Svetlana Gagarinova and Andrey Bulatov. Deep eutectic solvents as a new kind of dispersive solvent for dispersive liquid–liquid microextraction. RSC Advances. 2018. V. 8. P. 38146-38149. DOI: 10.1039/C8RA07300G
- Andrey Shishov, Natalia Volodina, Daria Nechaeva, Svetlana Gagarinova, Andrey Bulatov. An automated homogeneous liquid-liquid microextraction based on deep eutectic solvent for the HPLC-UV determination of caffeine in beverages. Microchemical Journal. 2018. V. 144. P. 469-473. DOI: 10.1016/j.microc.2018.10.014
- A.Y. Shishov, M.V. Chislov, D.V. Nechaeva, L.N. Moskvin, A.V. Bulatov. A new approach for microextraction of non-steroidal anti-inflammatory drugs from human urine samples based on in-situ deep eutectic mixture formation. Journal of Molecular Liquids. 2018. V. 272. P. 738-745. DOI: 10.1016/j.molliq.2018.10.006
- Aleksei Pochivalov, Polina Davletbaeva, Ksenia Cherkashina, Aleksey Lezov, Christina Vakh, Andrey Bulatov. Surfactant-mediated microextraction approach using switchable hydrophilicity solvent: HPLC-UV determination of Sudan dyes in solid food samples. Journal of Molecular Liquids. 2018. V. 271. P. 807-814. DOI: 10.1016/j.molliq.2018.09.072
- Christina Vakh, Aleksei Pochivalov, Stanislawa Koronkiewicz, Slawomir Kalinowski, Viktor Postnov, Andrey Bulatov. A chemiluminescence method for screening of fluoroquinolones in milk samples based on a multi-pumping flow system. Food Chemistry. 2019. V. 270. P.10-16. DOI: 10.1016/j.foodchem.2018.07.073
- Irina Timofeeva, Daria Kanashina, Dmitry Kirsanov, Andrey Bulatov. A heating-assisted liquid-liquid microextraction approach using menthol: Separation of benzoic acid in juice samples followed by HPLC-UV determination. Journal of Molecular Liquids. 2018. V. 261. P. 265-270. DOI: 10.1016/j.molliq.2018.04.040
- Ksenia Cherkashina, Christina Vakh , Sofya Lebedinets, Aleksei Pochivalov, Leonid Moskvin,Aleksey Lezov, Andrey Bulatov. An automated salting-out assisted liquid-liquid microextraction approach using 1-octylamine: On-line separation of tetracycline in urine samples followed by HPLC-UV determination. Talanta. 2018. V. 184. P. 122-127. DOI: 10.1016/j.talanta.2018.02.112
- Daria Nechaeva, Andrey Shishov, Sergey Ermakov, Andrey Bulatov. A paper-based analytical device for the determination of hydrogen sulfide in fuel oils based on headspace liquid-phase microextraction and cyclic voltammetry. Talanta. 2018. V. 183. P. 290-296. DOI: 10.1016/j.talanta.2018.02.074
- Andrey Shishov, Marcin Wieczorek, Paweł Kościelniak, Danuta Dudek-Adamska, Anna Telk, Leonid Moskvin, Andrey Bulatov. An automated continuous homogeneous microextraction for the determination of selenium and arsenic by hydride generation atomic fluorescence spectrometry. Talanta. 2018. V. 181. P. 359-365. DOI: 10.1016/j.talanta.2018.01.033
- Christina Vakh, Marcel Alaboud, Sofya Lebedinets, Dmitry Korolev, Viktor Postnov, Leonid Moskvin, Olga Osmolovskaya, Andrey Bulatov. An automated magnetic dispersive micro-solid phase extraction in a fluidized reactor for the determination of fluoroquinolonesin baby food samples. Analytica Chimica Acta. 2018. V. 1001. P. 59-69. DOI: 10.1016/j.aca.2017.11.065
2017
- Irina I. Timofeeva, Christina S. Vakh, Andrey V. Bulatov, Paul J. Worsfold. Flow analysis with chemiluminescence detection: recent advances and applications. Talanta. 2017. DOI: 10.1016/j.talanta.2017.11.007
- Andrey Shishov, Ivan Sviridov, Irina Timofeeva, Natalia Chibisova, Leonid Moskvin, Andrey Bulatov. An effervescence tablet-assisted switchable solvent-based microextraction: On-site preconcentration of steroid hormones in water samples followed by HPLC-UV determination. Journal of Molecular Liquids. 2017. DOI: 10.1016/j.molliq.2017.09.120
- Andrey Shishov, Andrey Bulatov, Marcello Locatelli, Simone Carradori, Vasil Andruch. Application of deep eutectic solvents in analytical chemistry. A review. Microchemical Journal. 2017. DOI: 10.1016/j.microc.2017.07.015
- Polina Davletbaeva, Petr Chocholouš, Andrey Bulatov, Dalibor Šatínský, Petr Solich. Sub–1 min separation in sequential injection chromatography for determination of synthetic water-soluble dyes in pharmaceutical formulation. Journal of Pharmaceutical and Biomedical Analysis. 2017. DOI: 10.1016/j.jpba.2017.05.036
- Irina Timofeeva, Daria Kanashina, Leonid Moskvin, Andrey Bulatov. An evaporation-assisted dispersive liquid–liquid microextraction technique as a simple tool for high performance liquid chromatography tandem–mass spectrometry determination of insecticides in wine. Journal of Chromatography A. 2017. DOI: 10.1016/j.chroma.2017.07.034
- Christina Vakh, Ekaterina Evdokimova, Aleksei Pochivalov, Leonid Moskvin, Andrey Bulatov. A novel flow injection chemiluminescence method for automated and miniaturized determination of phenols in smoked food samples. Food Chemistry. 2017. DOI: 10.1016/j.foodchem.2017.06.049
- Aleksei Pochivalov, Irina Timofeeva,Christina Vakh, Andrey Bulatov. Switchable hydrophilicity solvent membrane-based microextraction: HPLC-FLD determination of fluoroquinolones in shrimps. Analytica Chimica Acta. 2017. V. 976. P. 35-44. DOI: 10.1016/j.aca.2017.04.054.
- Aleksei Pochivalov, Christina Vakh, Vasil Andruch, Leonid Moskvin, Andrey Bulatov. Automated alkaline-induced salting-out homogeneous liquid-liquid extraction coupled with in-line organic-phase detection by an optical probe for the determination of diclofenac. Talanta. 2017. DOI: 10.1016/j.talanta.2017.03.074
- Lawrence Nugbienyo, Andrey Shishov, Sergei Garmonov, Leonid Moskvin, Vasil Andruch, Andrey Bulatov. Flow method based on liquid-liquid extraction using deep eutectic solvent for the spectrofluorimetric determination of procainamide in human saliva. Talanta. 2017. V. 168. P. 307-312. DOI: 10.1016/j.talanta.2017.03.057
- Andrey Shishov, Daria Nechaeva, Leonid Moskvin, Vasil Andruch, Andrey Bulatov. Automated solid sample dissolution coupled with sugaring-out homogenous liquid-liquid extraction. Application for the analysis of throat lozenge samples. Journal of Molecular Liquids. 2017. DOI: 10.1016/j.molliq.2017.03.022
- Lawrence Nugbienyo, Yulia Malinina, Sergei Garmonov, Mikhail Kamencev, Ilgiz Salahov, Vasil Andruch, Leonid Moskvin, Andrey Bulatov. Automated sugaring-out liquid-liquid extraction based on flow system coupled with HPLC-UV for the determination of procainamide in urine. Talanta. 2017. V. 167. P. 709-713. DOI: 10.1016/j.talanta.2017.02.051
- Christina Vakh, Stanislawa Koronkiewicz, Slawomir Kalinowski, Leonid Moskvin, Andrey Bulatov. An automatic chemiluminescence method based on the multi-pumping flow system coupled with the fluidized reactor and direct-injection detector: Determination of uric acid in saliva samples. Talanta. 2017. DOI: 10.1016/j.talanta.2017.02.009
- Irina Timofeeva, Semen Timofeev, Leonid Moskvin, Andrey Bulatov. A dispersive liquid-liquid microextraction using a switchable polarity dispersive solvent. Automated HPLC-FLD determination of ofloxacin in chicken meat. Analytica Chimica Acta. 2017. P. 35-42. DOI: 10.1016/j.aca.2016.11.018
- Irina Timofeeva, Andrey Shishov, Daria Kanashina, Daria Dzema, Andrey Bulatov. On-line in-syringe sugaring-out liquid-liquid extraction coupled with HPLC-MS/MS for the determination of pesticides in fruit and berry juices. Talanta. 2017. DOI: 10.1016/j.talanta.2017.01.008
- Andrey Shishov, Ilya Gorbunov, Andrey Bulatov, Fast flow-based method for automated and miniaturized determination of ferrocene in gasoline. Microchemical Journal 2017. V 130. P. 185–190. DOI: 10.1016/j.microc.2016.09.006