Department of Solid State Chemistry
Scientific group “Programmed layer-by-layer synthesis of multilayers of hybrid compounds and creation of new functional nanomaterials on their basis”
Group Members
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Valeri P. Tolstoyprofessor, D.Sci. This email address is being protected from spambots. You need JavaScript enabled to view it. |
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Larisa B. Gulinaassociate professor, This email address is being protected from spambots. You need JavaScript enabled to view it. |
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Alexandra A. Meleshkoresearcher, PhD This email address is being protected from spambots. You need JavaScript enabled to view it. |
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Leonid I. Kukloengineer, PhD |
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AnastasiaA. Golubeva, engineer |
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UlianaD. Chuvilo, master student |
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Kirill D. Nikitin, master student |
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Alexandra Zakaznova, undergraduate student |
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Ksenia Ermakova, undergraduate student |
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Tatiana Moskvina, undergraduate student |
Topics of scientific work
Theme 1: Creation of new routes for synthesis of multilayers of hybrid inorganic and organic compounds and obtaining new functional nanomaterials on their basis.
The project leader is Professor Valeri P. Tolstoy.
Theme 2: Synthesis of nanoscale crystals of inorganic compounds with the participation of chemical reactions at the gas-liquid interface.
The project leader is Associate Professor Larisa B. Gulina.
Theme 3: Development of new methods of synthesis of bioactive nanomaterials.
The project leader isresearch associateAlexandra A. Meleshko).
Theme 4: Development of new high-performance automated units for layer-by-layer synthesis of nanoscale structures.
The project leader is Leonid I.Kuklo.
Publications list
2024
- J. Mujtaba, A. Kuzin, G. Chen, F. Zhu, F.S. Fedorov, B. Mohan, G. Huang, V. Tolstoy, at al., Synergistic Integration of Hydrogen Peroxide Powered Valveless Micropumps and Membraneless Fuel Cells: A Comprehensive Review (2024) Advanced Materials Technologies 9 (14) 2302052, https://doi.org/10.1002/admt.202302052.
- A. Meleshko, V. Tolstoy, Redox Reactions in a Layer of Adsorbed Cu(II) and Fe(II) Ions and Synthesis of 2D CuFeO2 Ultrathin Nanosheets by Successive Ionic Layer Deposition (2024) Russ. J. Gen. Chem. 94 (Suppl 1), S13–S19, https://doi.org/10.1134/S1070363224140020.
- V. Tolstoy, K. Nikitin, A. Kuzin, F. Zhu, X. Li, G. Goltsman, D. Gorin, G. Huang, Rapid synthesis of Pt (0) motors-microscrolls on a nickel surface via H2PtCl6-induced galvanic replacement reaction (2024) Chem. Commun. 60 (23) 3182-3185, https://doi.org/10.1039/D3CC05766F.
- V. Tolstoy, E. Shilovskikh, L. Gulina, The effect of Ag(0) colloidal crystals and nanoribbons formation as a result of the redox reaction between Ce (III) and Ag (I) cations occurring on the surface of an aqueous solution of their salts mixture(2024) Nanosyst.: Phys., Chem., Mathem., 15 (1) 98-104, https://doi.org/10.17586/2220-8054-2024-15-1-98-103.
- M. Rastgoo-Deylami, A. Esfandiar, V. Tolstoy, Selenium-doped mixed metal oxide nanoparticles decorated on g-C3N4 and MXene sheets as promising bifunctional oxygen electrocatalysts for rechargeable Zn–air batteries (2024) Sust. Energy & Fuels 8 (9) 2038-2049, https://doi.org/10.1039/D3SE01419C.
- B. Zhong, M. Cai, S. Liu, J. He, J. Wang, K. Feng, V. Tolstoy, L. Jiang, C Li, at al., Modulation of the Structure‐function Relationship of the “nano‐greenhouse effect” towards Optimized Supra‐photothermal Catalysis (2024) Chem.–An Asian Journal, 19 (5) e202301077, https://doi.org/10.1002/asia.202301077.
- M. Kaneva, L. Gulina, V. Tolstoy, Study of the Formation Features of Pt (0) Nanoparticles at the Interface of Nickel–Aqueous Solution of Reagents under SILD Conditions and Their Electrocatalytic Properties (2024) Russ J. of Electrochem. 60 (3) 181-190, https://doi.org/10.1134/S1023193524030078.
- V. Tolstoy, D. Danilov, A. Meleshko, Effect of the formation of open microcapsules with Mn3O4 walls during hydrolysis of the MnSO4 salt solution droplets deposited on the alkaline solution surface (2024) Mend. Commun. 34 (3) 430-432, https://doi.org/10.1016/j.mencom.2024.04.038.
- S. Jaberi, P. Asen, A. Esfandiar, V. Tolstoy, MXene/carbon hybrid nanostructures and heteroatom-doped derivatives for enhanced electrochemical energy storage (2024) J. of Energy Storage 90, 111751, https://doi.org/10.1016/j.est.2024.111751.
- Y. Xiao, K. Feng, G. Dawson, V. Tolstoy, X. An, C. Li, L. He, A feasible interlayer strategy for simultaneous light and heat management in photothermal catalysis (2024) iScience 27 (6) 109792, https://doi.org/10.1016/j.isci.2024.109792.
- L. Gulina, V. Tolstoy, I. Murin, Crystallization of New Inorganic Fluoride Nanomaterials at Soft Chemistry Conditions and Their Application Prospects (2024) Russ. J. of Inorg. Chem., 1-12, https://doi.org/10.1134/S0036023623603070.
- V. Tolstoy, L. Gulina, E. Shilovskikh, 2D Nanocrystals of Zinc and Manganese (II, III) Oxides with Morphology of Perforated Nanoflakes Obtained Using Hydrolysis Reactions of Mn(OAc)2 and Zn(OAc)2 by Gaseous NH3 (2024) Russ. J. of Inorg. Chem., 69 (3) 311-318. https://doi.org/10.31857/S0044457X24030059.
- A. Golubeva, I. Kolesnikov, V. Tolstoy, Faсile synthesis of vase-like CeO2 microcapsules and their ordered arrays using the technique of spraying Ce(NO3)3 solution microdroplets on the alkali solution surface (2024) Ceram. Intern. (in press).
- L. Gulina, E. Shilovskikh, V. Tolstoy, Interface-assisted synthesis of Ag/Ceria composites for the detection and photodegradation of organic dyes (2024) Coll. and Surf.A:Physicochem. and Eng. Aspects, 701, 134897, https://doi.org/10.1016/j.colsurfa.2024.134897.
2023
- 1. V.P. Tolstoy, L.B. Gulina, A.A. Meleshko, 2D nanocrystals of metal oxides and hydroxides with nanosheet/nanoflake morphology in biomedicine, energy and chemistry (2023)Russ. Chem. Rev., 92 (3) RCR5071. DOI:10.57634/RCR5071.
- 2. L.B. Gulina, P.P. Senega, V.P. Tolstoy, Strategy for Patterning Titania Dendrites by Gas–Solution Interaction at Droplet Surfaces (2023)ACS Omega, 8 (37) pp. 33831-33837. DOI:10.1021/acsomega.3c04459.
- 3. G. Korotcenkov, V.P. Tolstoy, Current Trends in Nanomaterials for Metal Oxide-Based Conductometric Gas Sensors: Advantages and Limitations—Part 2: Porous 2D Nanomaterials (2023) Nanomaterials, 13 (2) 237. DOI:10.3390/nano13020237.
- 4. L.B. Gulina, I.A. Kasatkin, V.P. Tolstoy, D.V. Danilov, N.V. Platonova, I.V. Murin,
- Design of Pb1− xSr xF2 hollow crystals with gas–solution interfacial reactions (2023)
- CrystEngComm., 25 (47) pp. 6644-6649. DOI: 10.1039/D3CE00943B.
- 5. V.P. Tolstoy, M.V. Kaneva, Successive Ionic layers Deposition of Multilayers of [n(Co(OH)2–mPt(0)]k Nanocomposites and Their Structural and Chemical Features (2023)
- Russ. J. of Gen. Chem., 93 (1) pp. 85-90. DOI: 10.1134/S1070363223010127.
- 6. L.B. Gulina, P.O. Skripnyak, V.P. Tolstoy, Synthesis of ceria nanosheets on the surface of Ce (NO3)3 solution by interaction with gaseous ammonia (2023)Mend. Commun., 33 (1) pp. 124-126. DOI:10.1016/j.mencom.2023.01.039.
- 7. Biqing Zhong, Mujin Cai, Shuang Liu, Jiari He, Jiaqi Wang, Kai Feng, Valeri Tolstoy, Lin Jiang, Chaoran Li, Xingda An, and Le He, Modulation of the structure-function relationship of the “nanogreenhouse effect” towards optimized supra-photothermal catalysis (2023) Chem. an Asian Journal, e202301077. DOI:10.1002/asia.202301077.
2022
- 1. M.V. Kaneva, V.P. Tolstoy, Redox Reactions in a Layer of Adsorbed Mn (II) Cations and RuO4 Molecules. Synthesis of Manganese Oxide Doped with Ruthenium by Successive Ionic Layer Deposition (2022) Russ. J. of Gen. Chem., 92 (11) pp. 2339-2345. DOI:
- 10.1134/S1070363222110184.
- 2. E.V. Batishcheva, V.P. Tolstoy, Formation of Arrays of 1D Copper (II) Oxide Nanocrystals on the Nickel Surface upon Its Galvanic Replacement in a CuCl2 Solution and Their Electrocatalytic Properties (2022) Russ. J. of Inorg. Chem., 67 (6) pp. 898-903. DOI:10.1134/S0036023622060055.
- 3. V.P. Tolstoy, A.A. Meleshko, A.A. Golubeva, E.V. Bathischeva, The Effect of the Open Vase-like Microcapsules Formation with NiFe Double-Hydroxide Walls during Hydrolysis of the Mixture NiSO4 and FeSO4 Salt Solution (2022) Colloids and Interfaces, 6 (2) 32. DOI:10.3390/colloids6020032.
- 4. M.V. Kaneva, L.B. Gulina, V.P. Tolstoy, Pt nanoparticles synthesized by successive ionic layers deposition method and their electrocatalytic properties in hydrogen evolution reaction during water splitting (2022) Journal of Alloys and Compounds, 901, 163640. DOI:10.1016/j.jallcom.2022.163640.
- 5. M.V. Kaneva, A.A. Reveguk, V.P. Tolstoy, SILD-preparation of nanostructured Ru(0)x-RuO2· nH2O thin films: Effect of deposition cycles on electrocatalytic properties (2022) Ceram. Intern., 48 (8) pp. 11672-11677. DOI:10.1016/j.ceramint.2022.01.025.
- 6. V.P. Tolstoy, A.A. Golubeva, E.O. Kolomina, D.V. Navolotskaya, S.S. Ermakov, New Chemoresistive Gas Sensors with Active Elements Prepared by Layer-by-Layer Chemical Assembly with the Participation of Reagent Solutions and Their Analytical Capabilities (2022)
- Journal of Analytical Chemistry, 77 (3) pp. 257-276. DOI:10.31857/S0044450222030112.
- 7. V.P. Tolstoy, A.A. Meleshko, Hydrolysis of NiSO4 and FeSO4 Mixture in Microdrops of Their Aqueous Solution Deposited at the Surface of an Alkali Solution and Obtaining Vase-Like Microcapsules with Walls of … (2022) Russ. J. of Gen. Chem., 92 (2) pp. 276-280. DOI:10.1134/S1070363222020190.
- 8. M.V. Kaneva, E.V. Borisov, V.P. Tolstoy, Pt (0) microscrolls obtained on nickel surface by galvanic replacement reaction in H2PtCl6 solution as the basis for creating new SERS substrates (2022) Nanosystems: Physics, Chemistry, Mathematics, 13 (5), pp. 509-513. DOI: 10.17586/2220-8054-2022-13-5-509-513.
2021
- Mujtaba, J., Liu, J., Dey, K.K., Li, T., Chakraborty, R., Xu, K., Makarov, D., Barmin, R.A., Gorin, D.A., Tolstoy, V.P., Huang, G., Solovev, A.A., Mei, Y. Micro-Bio-Chemo-Mechanical-Systems: Micromotors, Microfluidics, and Nanozymes for Biomedical Applications (2021) Advanced Materials, 33 (22), article № 2007465, DOI: 10.1002/adma.202007465.
- Kaneva, M.V., Tolstoy, V.P. The “rolling up” effect of platinum layer obtained on nickel surface by interaction with solution of H2 H2PtCl6 and its electrocatalytic properties in hydrogen evolution reaction during water electrolysis in alkaline medium (2021) Nanosystems: Physics,Chemistry, Mathematics, 12 (5), pp. 630-633. DOI: 10.17586/2220-8054-2021-12-5-630-633.
- Naeem, S., Naeem, F., Mujtaba, J., Shukla, A.K., Mitra, S., Huang, G., Gulina, L., Rudakovskaya, P., Cui, J., Tolstoy, V., Gorin, D., Mei, Y., Solovev, A.A., Dey, K.K. Oxygen generation using catalytic nano/micromotors (2021) Micromachines, 12 (10), article № 1251. DOI: 10.3390/mi12101251.
- Gorokh, G., Bogomazova, N., Taleb, A., Zhylinski, V., Galkovsky, T., Zakhlebayeva, A., Lozovenko, A., Iji, M., Fedosenko, V., Tolstoy, V. Spatially ordered matrix of nanostructured tin–tungsten oxides nanocomposites formed by ionic layer deposition for gas sensing (2021) Sensors, 21 (12), article № 4169. DOI: 10.3390/s21124169.
- Popkov, V.I., Tolstoy, V.P. Controllable wettability tuning of the stainless steel surface through successive ionic layer deposition of Zn-Fe layered double hydroxysulfate (2021) Surface and Coatings Technology, 409, article № 126914. DOI: 10.1016/j.surfcoat.2021.126914.
2020
- Tolstoy V.P., Successive Ionic Layers Deposition. The Basic Aspects. (in Russian) SPb, 2020, 142 pp. (open access). https://elibrary.ru/item.asp?id=42596597.
- Strykanova, V.V., Gulina, L.B., Tolstoy, V.P., Tolstobrov, E.V., Danilov, D.V., Skvortsova, I. Synthesis of the FeOOH Microtubes with Inner Surface Modified by Ag Nanoparticles (2020) ACS Omega, 5 (25), pp. 15728-15733. DOI: 10.1021/acsomega.0c02258.
- Gulina, L.B., Tolstoy, V.P., Solovev, A.A., Gurenko, V.E., Huang, G., Mei, Y. Gas-Solution Interface Technique as a simple method to produce inorganic microtubes with scroll morphology, (2020) Progress in Natural Science: Materials International, 30 (3), pp. 279-288. DOI: 10.1016/j.pnsc.2020.05.001.
- Bahmei Fateme, Bahramifar Nader, Younesi Habibollah, Tolstoy Valeri, Synthesis of porous graphene nanocomposite and its excellent adsorption behavior for Erythromycin antibiotic, Nanosystems: Physics, Chemistry, Mathematics, 2020, 11 (2), P. 214–222.
- Gulina, L.B., Privalov, A.F., Weigler, M., Murin, I.V., Tolstoy, V., Vogel, M. Anomalously High Fluorine Mobility in Tysonite-Like LaF3:ScF3 Nanocrystals: NMR Diffusion Data, (2020) Applied Magnetic Resonance, DOI: 10.1007/s00723-020-01247-5.
- Meleshko, A.A., Tolstoy, V.P., Afinogenov, G.E., Levshakova, A.S., Afinogenova, A.G., Muldiyarov, V.P., Vissarionov, S.V., Linnik, S.A. Prospects of hydroxyapatite-based nanomaterials application synthesized by layer-by-layer method for pediatric traumatology and orthopedics (2020) Pediatric Traumatology, Orthopaedics and Reconstructive Surgery, 8 (2), pp. 217-230. DOI: 10.17816/PTORS33824.
- Absalan, Y., Alabada, R., Ryabov, M., Tolstoy, V., Butusov, L., Nikolskiy, V., Kopylov, V., Gholizadeh, M., Kovalchukova, O. Removing organic harmful compounds from the polluted water by a novel synthesized cobalt(II) and titanium(IV) containing photocatalyst under visible light (2020) Environmental Nanotechnology, Monitoring and Management, 14, paper # 100304, DOI: 10.1016/j.enmm.2020.100304.
- Tolstoy, V.P., Kaneva, M.V., Lobinsky, A.A., Koroleva, A.V. Direct successive ionic layer deposition of nanoscale iridium and tin oxide on titanium surface for electrocatalytic application in oxygen evolution reaction during water electrolysis in acidic medium (2020) Journal of Alloys and Compounds, 834, paper # 155205, DOI: 10.1016/j.jallcom.2020.155205.
- Gulina, L.B., Weigler, M., Privalov, A.F., Kasatkin, I.A., Groszewicz, P.B., Murin, I.V., Tolstoy, V.P., Vogel, M. Morphological and dynamical evolution of lanthanum fluoride 2D nanocrystals at thermal treatment (2020) Solid State Ionics, 352, paper #115354, DOI: 10.1016/j.ssi.2020.115354.
- Tolstoy, V., Kaneva, M., Fedotova, N., Levshakova, A. Low temperature synthesis of Сu0.3IrOx·nH2O nanocrystals by successive ionic layer deposition and their electrocatalytic properties in oxygen evolution reaction during water splitting in acidic medium (2020) Ceramics International, 46 (12), pp. 20122-20128, DOI: 10.1016/j.ceramint.2020.05.087.
- Popkov, V.I., Tolstoy, V.P., Semenov, V.G. Synthesis of phase-pure superparamagnetic nanoparticles of ZnFe2O4 via thermal decomposition of zinc-iron layered double hydroxysulphate (2020) Journal of Alloys and Compounds, 813, paper # 152179, DOI: 10.1016/j.jallcom.2019.152179.
2019
- Tolstoy, V.P., Vladimirova, N.I., Gulina, L.B. Formation of Ordered Honeycomb-like Structures of Manganese Oxide 2D Nanocrystals with the Birnessite-like Structure and Their Electrocatalytic Properties during Oxygen Evolution Reaction upon Water Splitting in an Alkaline Medium (2019) ACS Omega, 4 (26), pp. 22203-22208, DOI: 10.1021/acsomega.9b03499.
- Tolstoy, V.P., Vladimirova, N.I., Gulina, L.B. Ordered honeycomb-like network of MnO2·nH2O nanocrystals formed on the surface of a Mn(OAc)2 solution drop upon interaction with O3 gas (2019) Mendeleev Communications, 29 (6), pp. 713-715, DOI: 10.1016/j.mencom.2019.11.039.
- Gurenko, V., Gulina, L., Tolstoy, V. Sol–gel–xerogel transformations in the thin layer at the salt solution–gaseous reagent interface and the synthesis of new materials with microtubular morphology (2019) Journal of Sol-Gel Science and Technology, 92 (2), pp. 342-348, DOI: 10.1007/s10971-019-04949-w.
- Korotcenkov, G., Tolstoy, V., Brinzari, V. Morphological engineering of SnO2 and In2O3 films deposited by spray pyrolysis (2019) Bulletin of Materials Science, 42 (5), статья # 212, DOI: 10.1007/s12034-019-1910-5.
- Tolstoy, V.P., Kuklo, L.I., Gulina, L.B. Ni(II) doped FeOOH 2D nanocrystals, synthesized by Successive Ionic Layer Deposition, and their electrocatalytic properties during oxygen evolution reaction upon water splitting in the alkaline medium (2019) Journal of Alloys and Compounds, 786, pp. 198-204. DOI: 10.1016/j.jallcom.2019.01.324.
- Tolstoy, V.P., Lobinsky, A.A., Kaneva, M.V. Features of inorganic nanocrystals formation in conditions of successive ionic layers deposition in water solutions and the Co(II)Co(III) 2D layered double hydroxide synthesis (2019) Journal of Molecular Liquids, 282, pp. 32-38. DOI: 10.1016/j.molliq.2019.02.067.
- Popkov, V.I., Tolstoy, V.P., Omarov, S.O., Nevedomskiy, V.N. Enhancement of acidic-basic properties of silica by modification with CeO2-Fe2O3 nanoparticles via successive ionic layer deposition (2019) Applied Surface Science, 473, pp. 313-317. DOI: 10.1016/j.apsusc.2018.12.129.
- Gulina, L.B., Schikora, M., Privalov, A.F., Weigler, M., Tolstoy, V.P., Murin, I.V., Vogel, M. Influence of Morphology of LaF 3 Nano-crystals on Fluorine Dynamics Studied by NMR Diffusometry (2019) Applied Magnetic Resonance, 50 (4), pp. 579-588. DOI: 10.1007/s00723-018-1077-z.
- Popkov, V.I., Tolstoy, V.P., Nevedomskiy, V.N. Peroxide route to the synthesis of ultrafine CeO 2 -Fe 2 O 3 nanocomposite via successive ionic layer deposition (2019) Heliyon, 5 (3), статья #e01443, DOI: 10.1016/j.heliyon.2019.e01443.
- Tolstoy, V.P., Gulina, L.B., Golubeva, A.A., Ermakov, S.S., Gurenko, V.E., Navolotskaya, D.V., Vladimirova, N.I., Koroleva, A.V. Thin layers formed by the oriented 2D nanocrystals of birnessite-type manganese oxide as a new electrochemical platform for ultrasensitive nonenzymatic hydrogen peroxide detection (2019) Journal of Solid State Electrochemistry, 23 (2), pp. 573-582. DOI: 10.1007/s10008-018-04165-6.
- Lobinsky, A.A., Tolstoy, V.P. Synthesis of CoAl-LDH nanosheets and N-doped graphene nanocomposite via Successive Ionic Layer Deposition method and study of their electrocatalytic properties for hydrogen evolution in alkaline media (2019) Journal of Solid State Chemistry, 270, pp. 156-161. DOI: 10.1016/j.jssc.2018.09.041.
- Laptenkova, A.V., Tolstoy, V.P., Selyutin, A.A. Layer-by-layer synthesis of ferrocyanides of transition metals, as a new method of controlled self-assembly of cathodic materials (2019) AIP Conference Proceedings, 2064, paper #030008, DOI: 10.1063/1.5087670.
- Kodinzev, I., Lobinsky, A., Tolstoy, V. Successive ionic layer deposition of NiPx nanolayers on the surface of nickel foam and their electrocatalytic properties for oxygen evolution reaction upon water splitting in alkaline medium (2019) AIP Conference Proceedings, 2064, paper #030005, DOI: 10.1063/1.5087667.
- Gulina, L.B., Gurenko, V.E., Tolstoy, V.P., Mikhailovskii, V.Y., Koroleva, A.V. Interface-Assisted Synthesis of the Mn3-xFexO4 Gradient Film with Multifunctional Properties (2019) Langmuir, DOI: 10.1021/acs.langmuir.9b02338.
2018
- Gulina, L.B., Tolstoy, V.P., Lobinsky, A.A., Petrov, Y.V. Formation of Fe and Fe2O3 Microspirals via Interfacial Synthesis (2018) Particle and Particle Systems Characterization, 35 (9), статья #1800186, DOI: 10.1002/ppsc.201800186.
- Gulina, L.B., Tolstoy, V.P., Petrov, Y.V., Danilov, D.V. Interface-Assisted Synthesis of Single-Crystallрine ScF3 Microtubes (2018) Inorganic Chemistry, 57 (16), pp. 9779-9781. DOI: 10.1021/acs.inorgchem.8b01375.
- Gulina, L.B., Tolstoy, V.P., Kasatkin, I.A., Fateev, S.A. Flower-like silver nanocrystals: facile synthesis via a gas–solution interface technique (2018) Journal of Materials Science, 53 (11), pp. 8161-8169. DOI: 10.1007/s10853-018-2164-0.
- Gulina, L., Tolstoy, V., Kuklo, L., Mikhailovskii, V., Panchuk, V., Semenov, V. Synthesis of Fe(OH)3 Microtubes at the Gas–Solution Interface and Their Use for the Fabrication of Fe2O3 and Fe Microtubes (2018) European Journal of Inorganic Chemistry, 2018 (17), pp. 1842-1846. DOI: 10.1002/ejic.201800182.
- Lobinsky, A.A., Tolstoy, V.P. Synthesis of 2D Zn-Co LDH nanosheets by a successive ionic layer deposition method as a material for electrodes of high-performance alkaline battery-supercapacitor hybrid devices (2018) RSC Advances, 8 (52), pp. 29607-29612. DOI: 10.1039/c8ra00671g.
- A. A. Lobinsky, V. P. Tolstoy, I. A. Kodinzev, Electrocatalytic properties of NiOOH nanolayers, synthesized by successive ionic layer deposition, during the oxygen evolution reaction upon water splitting in the alkaline medium Nanosystems: Physics, Chemistry, Mathematics, 2018, 9 (5), P. 669–675, DOI 10.17586/22208054201895669675.
- Kasatkin, I.A., Gulina, L.B., Platonova, N.V., Tolstoy, V.P., Murin, I.V. Strong negative thermal expansion in the hexagonal polymorph of ScF3 (2018) CrystEngComm, 20 (20), pp. 2768-2771. DOI: 10.1039/c8ce00257f.
2017
- Gulina, L.B., Tolstoy, V.P., Tolstobrov, E.V. Facile synthesis of 2D silver nanocrystals by a gas–solution interface technique (2017) Mendeleev Communications, 27 (6), pp. 634-636. DOI: 10.1016/j.mencom.2017.11.033.
- Kodintsev, I., Tolstoy, V., Lobinsky, A. Room temperature synthesis of composite nanolayer consisting of AgMnO2 delafossite nanosheets and Ag nanoparticles by successive ionic layer deposition and their electrochemical properties (2017) Materials Letters, 196, pp. 54-56. DOI: 10.1016/j.matlet.2017.02.130.
- Lobinsky, A.A., Tolstoy, V.P. Synthesis of γ-MnOOH nanorods by successive ionic layer deposition method and their capacitive performance (2017) Journal of Energy Chemistry, 26 (3), pp. 336-339. DOI: 10.1016/j.jechem.2017.04.015.
- Tolstoy, V.P., Kodintsev, I.A., Reshanova, K.S., Lobinsky, A.A. A brief review of metal oxide (hydroxide)-graphene nanocomposites synthesis by layer-by-layer deposition from solutions and synthesis of CuO nanorods-graphene nanocomposite (2017) Reviews on Advanced Materials Science, 49 (1), pp. 28-37.
- Gulina, L.B., Tolstoy, V.P., Kasatkin, I.A., Murin, I.V. Facile synthesis of scandium fluoride oriented single-crystalline rods and urchin-like structures by a gas-solution interface technique (2017) CrystEngComm, 19 (36), pp. 5412-5416. DOI: 10.1039/c7ce01396e.
- V. E. Gurenko, V. P. Tolstoy, L. B. Gulina, The effect of microtube formation with walls, containing Fe3O4 nanoparticles, via gassolution interface technique by hydrolysis of the FeCl2 and FeCl3 mixed solution with gaseous ammonia, Nanosystems: Physics, Chemistry, Mathematics, 2017, 8 (4), P. 471–475.
- Gulina, L.B., Tolstoy, V.P., Kasatkin, I.A., Kolesnikov, I.E., Danilov, D.V. Formation of oriented LaF3 and LaF3:Eu3+ nanocrystals at the gas − Solution interface (2017) Journal of Fluorine Chemistry, 200, pp. 18-23. DOI: 10.1016/j.jfluchem.2017.05.006.
2016
- Gulina, L.B., Tolstoy, V.P., Lobinsky, A.A., Petrov, Y.V. The interaction of gaseous SiF4 and HF with surface of aqueous solution of LaCl3 leading to the formation of the LaF3–SiO2·nH2O nanocomposite and microtubes on its basis (2016) Russian Journal of General Chemistry, 86 (12), pp. 2689-2692. DOI: 10.1134/S1070363216120197.
- Kodintsev, I., Reshanova, K., Tolstoy, V. Layer-by-layer synthesis of metal oxide (or hydroxide)-graphene nanocomposites. the synthesis of CuO nanorods-graphene nanocomposite (2016) AIP Conference Proceedings, 1748, paper #040005, DOI: 10.1063/1.4954357.
- Lobinsky, A.A., Tolstoy, V.P., Gulina, L.B. A novel oxidation-reduction route for successive ionic layer deposition of NiO1+x·nH2O nanolayers and their capacitive performance (2016) Materials Research Bulletin, 76, pp. 229-234. DOI: 10.1016/j.materresbull.2015.12.023.
- Kuklo, L.I., Belyaninova, S.I., Ermakov, S.S., Tolstoy, V.P. Fe0.5MnOx·nH2O nanolayers synthesized via successive ionic layer deposition and their use in voltammetric nonenzymatic determination of hydrogen peroxide (2016) Nanotechnologies in Russia, 11 (3-4), pp. 137-143. DOI: 10.1134/S1995078016020105.
- Kuklo, L.I., Tolstoy, V.P. Redox reactions involving Ce3+ cations and FeO42- anions and the synthesis of Ce1.1FeOx·nH2O nanolayers by the SILD method (2016) Russian Journal of General Chemistry, 86 (1), pp. 1-4. DOI: 10.1134/S1070363216010011.
- Ermakov, S.S., Nikolaev, K.G., Tolstoy, V.P. Novel electrochemical sensors with electrodes based on multilayers fabricated by layer-by-layer synthesis and their analytical potential (2016) Russian Chemical Reviews, 85 (8), pp. 880-900. DOI: 10.1070/RCR4605.
- Gulina, L.B., Schäfer, M., Privalov, A.F., Tolstoy, V.P., Murin, I.V., Vogel, M. Synthesis and NMR investigation of 2D nanocrystals of the LaF3doped by SrF2 (2016) Journal of Fluorine Chemistry, 188, pp. 185-190. DOI: 10.1016/j.jfluchem.2016.07.006.
- Gulina, L.B., Pchelkina, A.A., Nikolaev, K.G., Navolotskaya, D.V., Ermakov, S.S., Tolstoy, V.P. A brief review on immobilization of gold nanoparticles on inorganic surfaces and Successive Ionic Layer Deposition (2016) Reviews on Advanced Materials Science, 44 (1), pp. 46-53.
Books
- V.P. Tolstoy, I.V. Chernyshova, V.A. Skryshevsky, Handbook of IR spectroscopy of ultra thin films. / New York: Wiley&Sons. 2003. 710 pp.
- V.P.Tolstoy, Sang Do Han, G.Korotcenkov, Successive Ionic Layer Deposition (SILD): Advanced Method for Deposition and Modification of Functional Nanostructured Metal Oxides Aimed for Gas Sensor Applications // METAL OXIDE NANOSTRUCTURES and THEIR APPLICATIONS. Chapter 9. California: American Scientific Publishers, 2010. V. 3. 384-436 P.
Grants
- RSF grant № 18-19-00370 “Development of the basics of nanotechnology for layer-by-layer synthesis of compounds from M_1M_2A_x series (M_1, M_2 = Ni, Co, Fe, Mn, Sn, Ir, etc., A = O, OH, etc.) and their composites with platinum group metals and/or carbon nanomaterials and creation of new electrode materials for alternative energy” (Project leader Prof. V. Tolstoy).
- RSF grant № 19-13-13018 “Crystallization at the interface between metal salt solution and gaseous reagent and obtaining a new generation of nanostructured inorganic materials” (Project leader research assistant A. Lobinsky).
- RSF grant № 19-73-00304 “Development of new routes for layer-by-layer synthesis of hydrated oxides M_xA_yBO_z and their nanocomposites with graphene” (Project leader Assoc. Prof. L. Gulina).
- Presidential grant for young scientists № МК-2860.2019.3 “Creation of new high-performance electrode materials for hybrid battery-supercapacitors” (Project leader research assistant A. Lobinsky).
- RFBR grant № 20-33-90228 “Study of regularities of layer-by-layer synthesis of nanosized rhodium and ruthenium particles, their alloys and nanocomposites with oxides of a number of transition metals with general formulas M_1^0, M_1-xM_2 and M_1O_x-nM_2O_y (M_1= Rh, Ru, M_2 = Co, Ni, Cu, etc.) and creation of new practically important functional nanomaterials” (Project leader Prof. V. Tolstoy).
- Grant from the St. Petersburg Committee for Science and Higher Education of the St. Petersburg Government, contract № 125-20 (2020) «Development of methods for layer-by-layer synthesis of iron and zinc oxyhydroxide nanolayers and study of their bactericidal properties» (Project leader research assistant A. Meleshko).
- RSF grant № 18-19-00370P (prolongation for the period 2021-2022)“Development of the basics of nanotechnology for layer-by-layer synthesis of compounds from M_1M_2A_x series (M_1, M_2 = Ni, Co, Fe, Mn, Sn, Ir, etc., A = O, OH, etc.) and their composites with platinum group metals and/or carbon nanomaterials and creation of new electrode materials for alternative energy” (Project leader Prof. V. Tolstoy).
- RSF grant № 22-29-00687 “Optimization of the process of obtaining functional-gradient and tubular inorganic microstructures as a result of chemical reactions at the liquid-gas interface” (Project leader Assoc. Prof. L. Gulina).
- Grant from SPbSU-Sharif University of Technology (Iran), Pure ID:93573974 “Creation of new 2D-nanomaterials for electrochemical energy storage and conversion systems using the methodology of layer-by-layer chemical assembly in reagent solutions” (Project leader Prof. V. Tolstoy).
- RSF grant № 23-23-00060 “Creation of new routes for layer-by-layer synthesis of complex oxides of Cu(II), Ag(I), Zn(II), Fe(II,III), etc. and their hybrid compounds with bioorganic molecules and study of their bactericidal properties” (Project leader research assistant A. Meleshko).
- RSF grant №23-19-00566 “Development of technological bases of programmed layer-by-layer synthesis of complex oxides Ce(III, IV), Mn(III,IV) and their composites with biopolymers and hydroxyapatite and creation of new biomedical materials” (Project leader Prof. V. Tolstoy).
…etc.